Effect of Reduction Treatment on Structural Properties of TiO2 Supported Pt Nanoparticles and Their Catalytic Activity for Benzene Oxidation
文献类型：期刊论文
| 作者 | Li, Zenghe1; Yang, Kun1,2; Liu, Gang2,3; Deng, Gaofeng1; Li, Jiaqi2,3; Li, Ge1; Yue, Renliang2; Yang, Jun2; Chen, Yunfa2 |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 144期号:6页码:1080-1087 |
| 关键词 | Pt-TiO2 Nanoparticles Catalysis Benzene oxidation Chemisorbed oxygen |
| ISSN号 | 1011-372X |
| 其他题名 | Catal. Lett. |
| 中文摘要 | A series of highly active Pt-TiO2 catalysts have been prepared by impregnation methods via different reduction processes and used for catalytic decomposition of benzene. The oxidized and reduced Pt-TiO2 catalysts exhibit apparent differences in physical/chemical features (e.g. particle size, chemical state, and electronic property of Pt nanoparticles, and surface oxygen) and catalytic activities for benzene oxidation. Nearly 100 % benzene conversion is achieved on Pt-TiO2 catalysts obtained by the sodium citrate (C6H5Na3O7 center dot 2H(2)O, Na(3)Ct) reduction at approximate 160 A degrees C. Metallic Pt nanoparticles have strong capacity for oxygen activation, and the negative charges and rich chemisorbed oxygen on the surface of metallic Pt nanoparticles are probably responsible for their high catalytic activities for benzene oxidation. 1 wt% Pt-TiO2 catalysts have been prepared by impregnation methods via different reduction processes and used for catalytic decomposition of benzene. The oxidized and reduced catalysts exhibit apparent differences in physical/chemical features and catalytic activities for benzene oxidation. Metallic Pt nanoparticles have strong capacity for oxygen activation, and the negative charges and rich chemisorbed oxygen on the surface of metallic Pt nanoparticles are probably responsible for their high catalytic activities for benzene oxidation. |
| 英文摘要 | A series of highly active Pt-TiO2 catalysts have been prepared by impregnation methods via different reduction processes and used for catalytic decomposition of benzene. The oxidized and reduced Pt-TiO2 catalysts exhibit apparent differences in physical/chemical features (e.g. particle size, chemical state, and electronic property of Pt nanoparticles, and surface oxygen) and catalytic activities for benzene oxidation. Nearly 100 % benzene conversion is achieved on Pt-TiO2 catalysts obtained by the sodium citrate (C6H5Na3O7 center dot 2H(2)O, Na(3)Ct) reduction at approximate 160 A degrees C. Metallic Pt nanoparticles have strong capacity for oxygen activation, and the negative charges and rich chemisorbed oxygen on the surface of metallic Pt nanoparticles are probably responsible for their high catalytic activities for benzene oxidation. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | FREE AQUEOUS-SOLUTION ; SELECTIVE OXIDATION ; AU NANOPARTICLES ; ROOM-TEMPERATURE ; FORMALDEHYDE ; TOLUENE ; COMBUSTION ; ACTIVATION ; GLYCEROL ; OXYGEN |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000335666300015 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10932]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Beijing Univ Chem Technol, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zenghe,Yang, Kun,Liu, Gang,et al. Effect of Reduction Treatment on Structural Properties of TiO2 Supported Pt Nanoparticles and Their Catalytic Activity for Benzene Oxidation[J]. CATALYSIS LETTERS,2014,144(6):1080-1087. |
| APA | Li, Zenghe.,Yang, Kun.,Liu, Gang.,Deng, Gaofeng.,Li, Jiaqi.,...&Chen, Yunfa.(2014).Effect of Reduction Treatment on Structural Properties of TiO2 Supported Pt Nanoparticles and Their Catalytic Activity for Benzene Oxidation.CATALYSIS LETTERS,144(6),1080-1087. |
| MLA | Li, Zenghe,et al."Effect of Reduction Treatment on Structural Properties of TiO2 Supported Pt Nanoparticles and Their Catalytic Activity for Benzene Oxidation".CATALYSIS LETTERS 144.6(2014):1080-1087. |
入库方式： OAI收割
来源：过程工程研究所
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