Microwave-assisted conversion of microcrystalline cellulose to 5-hydroxymethylfurfural catalyzed by ionic liquids
文献类型：期刊论文
| 作者 | Qu, Yongshui1; Wei, Quanyuan2,3; Li, Hongqiang1; Oleskowicz-Popiel, Piotr4; Huang, Chongpin3; Xu, Jian1 |
| 刊名 | BIORESOURCE TECHNOLOGY
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 162期号:1页码:358-364 |
| 关键词 | 5-HMF Ionic liquids Microwave irradiation RSM optimization Microcrystalline cellulose |
| ISSN号 | 0960-8524 |
| 其他题名 | Bioresour. Technol. |
| 中文摘要 | Ionic liquid (IL) has been widely investigated in 5-HMF production from biomass. However, most of studies employed IL as reaction solvent which requires a large amount of IL. In the present study, IL was utilized as catalyst in the conversion of microcrystalline cellulose (MCC) to 5-HMF under microwave irradiation (MI) in N, N-dimethylacetamide (DMAc) containing LiCl. 1,1,3,3-tetramethylguanidine (TMG)-based ILs, including 1,1,3,3-tetramethylguanidine tetrafluoroborate ([TMG][BF4]) and 1,1,3,3-tetramethylguanidine lactate ([TMG] L) which were commonly used in the absorption of SO2 and CO2 from flue gas, were synthesized and applied in the conversion of MCC to 5-HMF for the first time. Of the catalysts employed, [TMG] BF4 showed high catalytic activity in 5-HMF production from MCC. The condition including the ratio of IL to MCC, temperature and time for MCC conversion was optimized using Central Composite Design (CCD) and Response Surface Methodology (RSM). The highest 5-HMF yield of 28.63% was achieved with the optimal condition. (C) 2014 Elsevier Ltd. All rights reserved. |
| 英文摘要 | Ionic liquid (IL) has been widely investigated in 5-HMF production from biomass. However, most of studies employed IL as reaction solvent which requires a large amount of IL. In the present study, IL was utilized as catalyst in the conversion of microcrystalline cellulose (MCC) to 5-HMF under microwave irradiation (MI) in N, N-dimethylacetamide (DMAc) containing LiCl. 1,1,3,3-tetramethylguanidine (TMG)-based ILs, including 1,1,3,3-tetramethylguanidine tetrafluoroborate ([TMG][BF4]) and 1,1,3,3-tetramethylguanidine lactate ([TMG] L) which were commonly used in the absorption of SO2 and CO2 from flue gas, were synthesized and applied in the conversion of MCC to 5-HMF for the first time. Of the catalysts employed, [TMG] BF4 showed high catalytic activity in 5-HMF production from MCC. The condition including the ratio of IL to MCC, temperature and time for MCC conversion was optimized using Central Composite Design (CCD) and Response Surface Methodology (RSM). The highest 5-HMF yield of 28.63% was achieved with the optimal condition. (C) 2014 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Technology |
| 类目[WOS] | Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| 研究领域[WOS] | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| 关键词[WOS] | EFFICIENT DEHYDRATION ; ENZYMATIC-HYDROLYSIS ; DIMETHYL-SULFOXIDE ; METAL CHLORIDES ; BIOMASS ; FRUCTOSE ; ACID ; OPTIMIZATION ; PRETREATMENT ; IRRADIATION |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000335909700047 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10954]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Beijing Municipal Res Acad Environm Protect, Beijing 100037, Peoples R China 3.Beijing Univ Chem Technol, Beijing 100029, Peoples R China 4.Poznan Univ Tech, Fac Civil & Environm Engn, Inst Environm Engn, PL-60965 Poznan, Poland |
| 推荐引用方式 GB/T 7714 | Qu, Yongshui,Wei, Quanyuan,Li, Hongqiang,et al. Microwave-assisted conversion of microcrystalline cellulose to 5-hydroxymethylfurfural catalyzed by ionic liquids[J]. BIORESOURCE TECHNOLOGY,2014,162(1):358-364. |
| APA | Qu, Yongshui,Wei, Quanyuan,Li, Hongqiang,Oleskowicz-Popiel, Piotr,Huang, Chongpin,&Xu, Jian.(2014).Microwave-assisted conversion of microcrystalline cellulose to 5-hydroxymethylfurfural catalyzed by ionic liquids.BIORESOURCE TECHNOLOGY,162(1),358-364. |
| MLA | Qu, Yongshui,et al."Microwave-assisted conversion of microcrystalline cellulose to 5-hydroxymethylfurfural catalyzed by ionic liquids".BIORESOURCE TECHNOLOGY 162.1(2014):358-364. |
入库方式： OAI收割
来源：过程工程研究所
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