Anion-Based pH Responsive Ionic Liquids: Design, Synthesis, and Reversible Self-Assembling Structural Changes in Aqueous Solution
文献类型：期刊论文
| 作者 | Wang, Huiyong1; Tan, Bo1; Wang, Jianji1; Li, Zhiyong1; Zhang, Suojiang2 |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2014-04-15 |
| 卷号 | 30期号:14页码:3971-3978 |
| 关键词 | AGGREGATION BEHAVIOR DRUG-DELIVERY TEMPERATURE NANOPARTICLES SURFACTANT MICELLES VESICLES RELEASE WATER |
| ISSN号 | 0743-7463 |
| 其他题名 | Langmuir |
| 中文摘要 | The creation of pH responsive materials that undergo morphological transitions between micelle and vesicle induced by solution pH change is of great importance for their potential application in drug delivery and biochemical engineering. Here, we have developed a series of 18 pH responsive ionic liquids composed of 1-alkyl-3-methylimidazolium cation, [C(n)mim](+) (n = 4, 6, 8, 10, 12, 14), and different pH responsive anions such as potassium phthalic acid ([C6H4COOKCOO](-)), sodium sulfosalicylic acid ([C6H3OHCOOSO3Na](-)), and sodium m-carboxyl-benzenesulfonate ([C6H4COOSO3Na](-)). The aggregation behavior and self-assembly structures of the ILs in aqueous solution have been investigated by surface tension, dynamic light scattering, transmission electron microscopy, small-angle X-ray scattering, and nuclear magnetic resonance spectroscopy. It was found for the first time that single tail ionic liquids, [C(n)mim]X (n = 12 and 14, X = [C6H4COOKCOO], [C6H3OHCOOSO3Na], and [C6H4COOSO3Na]) could form vesicles without any additives, and reversible transition was observed between spherical micelles and vesicles with the change of solution pH value. The transition in self-assembly structures is suggested to be driven by the variation in molecular structure and hydrophilicity/hydrophobicity of anions of the ILs. |
| 英文摘要 | The creation of pH responsive materials that undergo morphological transitions between micelle and vesicle induced by solution pH change is of great importance for their potential application in drug delivery and biochemical engineering. Here, we have developed a series of 18 pH responsive ionic liquids composed of 1-alkyl-3-methylimidazolium cation, [C(n)mim](+) (n = 4, 6, 8, 10, 12, 14), and different pH responsive anions such as potassium phthalic acid ([C6H4COOKCOO](-)), sodium sulfosalicylic acid ([C6H3OHCOOSO3Na](-)), and sodium m-carboxyl-benzenesulfonate ([C6H4COOSO3Na](-)). The aggregation behavior and self-assembly structures of the ILs in aqueous solution have been investigated by surface tension, dynamic light scattering, transmission electron microscopy, small-angle X-ray scattering, and nuclear magnetic resonance spectroscopy. It was found for the first time that single tail ionic liquids, [C(n)mim]X (n = 12 and 14, X = [C6H4COOKCOO], [C6H3OHCOOSO3Na], and [C6H4COOSO3Na]) could form vesicles without any additives, and reversible transition was observed between spherical micelles and vesicles with the change of solution pH value. The transition in self-assembly structures is suggested to be driven by the variation in molecular structure and hydrophilicity/hydrophobicity of anions of the ILs. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Chemistry, Physical ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Materials Science |
| 关键词[WOS] | AGGREGATION BEHAVIOR ; DRUG-DELIVERY ; TEMPERATURE ; NANOPARTICLES ; SURFACTANT ; MICELLES ; VESICLES ; RELEASE ; WATER |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000334657800007 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10974]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Henan Normal Univ, Key Lab Green Chem Media & React, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn,Minist Educ, Xinxiang 453007, Henan, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Huiyong,Tan, Bo,Wang, Jianji,et al. Anion-Based pH Responsive Ionic Liquids: Design, Synthesis, and Reversible Self-Assembling Structural Changes in Aqueous Solution[J]. LANGMUIR,2014,30(14):3971-3978. |
| APA | Wang, Huiyong,Tan, Bo,Wang, Jianji,Li, Zhiyong,&Zhang, Suojiang.(2014).Anion-Based pH Responsive Ionic Liquids: Design, Synthesis, and Reversible Self-Assembling Structural Changes in Aqueous Solution.LANGMUIR,30(14),3971-3978. |
| MLA | Wang, Huiyong,et al."Anion-Based pH Responsive Ionic Liquids: Design, Synthesis, and Reversible Self-Assembling Structural Changes in Aqueous Solution".LANGMUIR 30.14(2014):3971-3978. |
入库方式： OAI收割
来源：过程工程研究所
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