Electrocatalysis of carbon black- or poly(diallyldimethylammonium chloride)-functionalized activated carbon nanotubes-supported Pd-Tb towards methanol oxidation in alkaline media
文献类型：期刊论文
| 作者 | Wang, Li1,2; Wang, Yi1; Li, An2; Yang, Yunshang2; Tang, Qinghu3; Cao, Hongbin1; Qi, Tao1; Li, Changming4 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 257期号:1页码:138-146 |
| 关键词 | Pd-Tb/C Electrocatalysts Methanol oxidation Activated carbon nanotubes Poly(diallyldimethylammonium chloride) |
| ISSN号 | 0378-7753 |
| 其他题名 | J. Power Sources |
| 中文摘要 | The Pd-Tb/C catalysts with different Pd/Tb ratios were synthesized by a simple simultaneous reduction reaction with sodium borohydride in aqueous solution. The structure and morphology of those catalysts had been characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrocatalytic performance of those catalysts for methanol oxidation in alkaline media was investigated using cyclic voltammetry (CV), linear sweep voltammetry (LSV) and CO stripping experiments. It is found that the 20%Pd-1%Tb/C catalyst has a higher catalytic activity than the 20%Pd/C catalyst, but the effect of Tb cannot be explained by a bi-functional mechanism. According to the X-Ray photoelectron spectroscopy (XPS) analyses, it is suggested that the higher content of metallic Pd caused by the addition of Tb contributes to the better catalytic activity of 20%Pd-1%Tb/C. Based on the good electrocatalytic performance of 20%Pd-1%Tb/C, the 20%Pd-1%Tb catalyst supported on poly(diallyldimethylammonium chloride) (PDDA)-functionalized activated carbon nanotubes was prepared, and it exhibits a better catalytic activity. The improvement mainly results from the further increase of metallic Pd due to the presence of PDDA. (C) 2014 Elsevier B.V. All rights reserved. |
| 英文摘要 | The Pd-Tb/C catalysts with different Pd/Tb ratios were synthesized by a simple simultaneous reduction reaction with sodium borohydride in aqueous solution. The structure and morphology of those catalysts had been characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrocatalytic performance of those catalysts for methanol oxidation in alkaline media was investigated using cyclic voltammetry (CV), linear sweep voltammetry (LSV) and CO stripping experiments. It is found that the 20%Pd-1%Tb/C catalyst has a higher catalytic activity than the 20%Pd/C catalyst, but the effect of Tb cannot be explained by a bi-functional mechanism. According to the X-Ray photoelectron spectroscopy (XPS) analyses, it is suggested that the higher content of metallic Pd caused by the addition of Tb contributes to the better catalytic activity of 20%Pd-1%Tb/C. Based on the good electrocatalytic performance of 20%Pd-1%Tb/C, the 20%Pd-1%Tb catalyst supported on poly(diallyldimethylammonium chloride) (PDDA)-functionalized activated carbon nanotubes was prepared, and it exhibits a better catalytic activity. The improvement mainly results from the further increase of metallic Pd due to the presence of PDDA. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Electrochemistry ; Energy & Fuels |
| 研究领域[WOS] | Electrochemistry ; Energy & Fuels |
| 关键词[WOS] | FORMIC-ACID ELECTROOXIDATION ; REDUCED GRAPHENE OXIDE ; FUEL-CELLS ; ETHANOL OXIDATION ; CATALYSTS ; NANOPARTICLES ; PERFORMANCE ; NANOCOMPOSITES ; ENERGIES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000333780000018 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10977]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China 3.Henan Normal Univ, Minist Educ, Sch Chem & Chem Engn, Key Lab Green Chem Media & React, Xinxiang 453007, Peoples R China 4.Southwest Univ, Inst Clean Energy & Adv Mat, Chongqing 400715, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Li,Wang, Yi,Li, An,et al. Electrocatalysis of carbon black- or poly(diallyldimethylammonium chloride)-functionalized activated carbon nanotubes-supported Pd-Tb towards methanol oxidation in alkaline media[J]. JOURNAL OF POWER SOURCES,2014,257(1):138-146. |
| APA | Wang, Li.,Wang, Yi.,Li, An.,Yang, Yunshang.,Tang, Qinghu.,...&Li, Changming.(2014).Electrocatalysis of carbon black- or poly(diallyldimethylammonium chloride)-functionalized activated carbon nanotubes-supported Pd-Tb towards methanol oxidation in alkaline media.JOURNAL OF POWER SOURCES,257(1),138-146. |
| MLA | Wang, Li,et al."Electrocatalysis of carbon black- or poly(diallyldimethylammonium chloride)-functionalized activated carbon nanotubes-supported Pd-Tb towards methanol oxidation in alkaline media".JOURNAL OF POWER SOURCES 257.1(2014):138-146. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。