Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol
文献类型：期刊论文
| 作者 | Wang, Liguo1; Li, Huiquan1; Xin, Shumin1; Li, Fengjiao1,2 |
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2014-05-05 |
| 卷号 | 50期号:1页码:49-53 |
| 关键词 | Solid base Slag Diethyl carbonate Ethyl carbamate Ethanolysis |
| ISSN号 | 1566-7367 |
| 其他题名 | Catal. Commun. |
| 中文摘要 | The solid base derived from abundant waste slag was prepared by co-precipitation method, and tested in the diethyl carbonate synthesis via ethanolysis of ethyl carbamate. Compared to the previous reports, much higher catalytic activity and turnover frequency (TOF) of 2926 mg(DEC)/g(cat) center dot h(-1) could be achieved. Accordingly, the correlation between the catalyst basic properties and the catalytic performance revealed that the appropriate strong basic sites facilitated the formation of DEC. Moreover, the catalyst could be readily recycled and reused for several times through facile calcination. (C) 2014 Published by Elsevier B.V. |
| 英文摘要 | The solid base derived from abundant waste slag was prepared by co-precipitation method, and tested in the diethyl carbonate synthesis via ethanolysis of ethyl carbamate. Compared to the previous reports, much higher catalytic activity and turnover frequency (TOF) of 2926 mg(DEC)/g(cat) center dot h(-1) could be achieved. Accordingly, the correlation between the catalyst basic properties and the catalytic performance revealed that the appropriate strong basic sites facilitated the formation of DEC. Moreover, the catalyst could be readily recycled and reused for several times through facile calcination. (C) 2014 Published by Elsevier B.V. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TRANSESTERIFICATION ; TEMPERATURE |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000336116700012 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10979]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc & Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Liguo,Li, Huiquan,Xin, Shumin,et al. Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol[J]. CATALYSIS COMMUNICATIONS,2014,50(1):49-53. |
| APA | Wang, Liguo,Li, Huiquan,Xin, Shumin,&Li, Fengjiao.(2014).Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol.CATALYSIS COMMUNICATIONS,50(1),49-53. |
| MLA | Wang, Liguo,et al."Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol".CATALYSIS COMMUNICATIONS 50.1(2014):49-53. |
入库方式： OAI收割
来源：过程工程研究所
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