Formation of C-C bonds for the production of bio-alkanes under mild conditions
文献类型：期刊论文
| 作者 | Xin, Jiayu1; Zhang, Suojiang1; Yan, Dongxia1; Ayodele, Olubunmi1; Lu, Xingmei1; Wang, Jianji2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:7页码:3589-3595 |
| 关键词 | CATALYTIC CONVERSION LIGNOCELLULOSIC BIOMASS FORMIC-ACID TRANSPORTATION FUELS GAMMA-VALEROLACTONE LEVULINIC ACID CHEMICALS HYDRODEOXYGENATION HYDROCARBONS CELLULOSE |
| ISSN号 | 1463-9262 |
| 其他题名 | Green Chem. |
| 中文摘要 | It is of crucial importance to form C-C bonds between biomass-derived compounds for the production of bio-alkanes from biomass. In this study, it was found that C-C bonds can be formed between angelica lactones, key intermediates derived from biomass, through free radical reactions under mild conditions without using a noble catalyst or solvent, which gave elongated carbon chains of di/trimers with 10 or 15 carbons, with complete conversion and 100% selectivity. The di/trimers produced serve as a novel feed stock for the carbon backbones of bio-alkanes. Hydrogenation of the di/trimers produced C6-C13 hydrocarbons suitable for use as transportation fuels. |
| 英文摘要 | It is of crucial importance to form C-C bonds between biomass-derived compounds for the production of bio-alkanes from biomass. In this study, it was found that C-C bonds can be formed between angelica lactones, key intermediates derived from biomass, through free radical reactions under mild conditions without using a noble catalyst or solvent, which gave elongated carbon chains of di/trimers with 10 or 15 carbons, with complete conversion and 100% selectivity. The di/trimers produced serve as a novel feed stock for the carbon backbones of bio-alkanes. Hydrogenation of the di/trimers produced C6-C13 hydrocarbons suitable for use as transportation fuels. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CATALYTIC CONVERSION ; LIGNOCELLULOSIC BIOMASS ; FORMIC-ACID ; TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; LEVULINIC ACID ; CHEMICALS ; HYDRODEOXYGENATION ; HYDROCARBONS ; CELLULOSE |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000338298600024 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/10996]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Henan Normal Univ, Sch Chem & Environm Sci, Minist Educ, Key Lab Green Chem Media & React, Xinxiang 453007, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xin, Jiayu,Zhang, Suojiang,Yan, Dongxia,et al. Formation of C-C bonds for the production of bio-alkanes under mild conditions[J]. GREEN CHEMISTRY,2014,16(7):3589-3595. |
| APA | Xin, Jiayu,Zhang, Suojiang,Yan, Dongxia,Ayodele, Olubunmi,Lu, Xingmei,&Wang, Jianji.(2014).Formation of C-C bonds for the production of bio-alkanes under mild conditions.GREEN CHEMISTRY,16(7),3589-3595. |
| MLA | Xin, Jiayu,et al."Formation of C-C bonds for the production of bio-alkanes under mild conditions".GREEN CHEMISTRY 16.7(2014):3589-3595. |
入库方式： OAI收割
来源：过程工程研究所
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