中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of Thiourea Functionalized Polyvinyl Alcohol-Coated Magnetic Nanoparticles and Their Application in Pb2+ Ions Adsorption

文献类型:期刊论文

作者Xiong, Wubin1; Guan, Yueping1; Guo, Chen2; Yang, Mingzhu1; Xia, Tingting1; Zhao, Shen1
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2014-09-15
卷号131期号:18页码:9
关键词adsorption magnetism and magnetic properties nanoparticles nanowires and nanocrystals surfaces and interfaces
ISSN号0021-8995
其他题名J. Appl. Polym. Sci.
中文摘要We have prepared a novel kind of magnetic nanoparticle with high adsorption capacity and good selectivity for Pb2+ ions by modifying the magnetic nanoparticles with polyvinyl alcohol (PVA) and thiourea. The resultant magnetic nanoparticles were used to adsorb Pb2+ ions from aqueous solution. The influence of the solution pH, the adsorption time, the adsorption temperature, coexisting ions, and the initial concentration of Pb2+ ions on the adsorption of Pb2+ ions were investigated. The results indicated that Pb2+ ions adsorption was an endothermic reaction, and adsorption equilibrium was achieved within 30 min. The optimal pH for the adsorption of Pb 21 ions was pH 5.5, and the maximum adsorption capacity of Pb2+ ions was found to be 220 mg/g. Moreover, the coexisting cations such as Ca2+, Co2+, and Ni2+ had little effect on adsorption of Pb2+ ions. The regeneration studies showed that thiourea functionalized PVA-coated magnetic nanoparticles could be reused for the adsorption of Pb 21 ions from aqueous solutions over five cycles without remarkable change in the adsorption capacity. (C) 2014 Wiley Periodicals, Inc.
英文摘要We have prepared a novel kind of magnetic nanoparticle with high adsorption capacity and good selectivity for Pb2+ ions by modifying the magnetic nanoparticles with polyvinyl alcohol (PVA) and thiourea. The resultant magnetic nanoparticles were used to adsorb Pb2+ ions from aqueous solution. The influence of the solution pH, the adsorption time, the adsorption temperature, coexisting ions, and the initial concentration of Pb2+ ions on the adsorption of Pb2+ ions were investigated. The results indicated that Pb2+ ions adsorption was an endothermic reaction, and adsorption equilibrium was achieved within 30 min. The optimal pH for the adsorption of Pb 21 ions was pH 5.5, and the maximum adsorption capacity of Pb2+ ions was found to be 220 mg/g. Moreover, the coexisting cations such as Ca2+, Co2+, and Ni2+ had little effect on adsorption of Pb2+ ions. The regeneration studies showed that thiourea functionalized PVA-coated magnetic nanoparticles could be reused for the adsorption of Pb 21 ions from aqueous solutions over five cycles without remarkable change in the adsorption capacity. (C) 2014 Wiley Periodicals, Inc.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]HEAVY-METALS REMOVAL ; AQUEOUS-SOLUTION ; WASTE-WATER ; ADSORBENT ; CHROMIUM ; KINETICS ; PB(II) ; EPICHLOROHYDRIN ; MICROSPHERES ; EQUILIBRIUM
收录类别SCI
原文出处://WOS:000337623600037
语种英语
WOS记录号WOS:000337623600037
公开日期2014-08-28
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/10998]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Lab Separat Sci & Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Xiong, Wubin,Guan, Yueping,Guo, Chen,et al. Preparation of Thiourea Functionalized Polyvinyl Alcohol-Coated Magnetic Nanoparticles and Their Application in Pb2+ Ions Adsorption[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2014,131(18):9.
APA Xiong, Wubin,Guan, Yueping,Guo, Chen,Yang, Mingzhu,Xia, Tingting,&Zhao, Shen.(2014).Preparation of Thiourea Functionalized Polyvinyl Alcohol-Coated Magnetic Nanoparticles and Their Application in Pb2+ Ions Adsorption.JOURNAL OF APPLIED POLYMER SCIENCE,131(18),9.
MLA Xiong, Wubin,et al."Preparation of Thiourea Functionalized Polyvinyl Alcohol-Coated Magnetic Nanoparticles and Their Application in Pb2+ Ions Adsorption".JOURNAL OF APPLIED POLYMER SCIENCE 131.18(2014):9.

入库方式: OAI收割

来源:过程工程研究所

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