Immobilization and molecular rearrangement of ionic liquids on the surface of carbon nanotubes
文献类型：期刊论文
| 作者 | Zhao, Cuifang1,2; Ren, Baozeng1; Song, Yuting2; Zhang, Junling2; Wei, Lingchao1; Chen, Shimou2; Zhang, Suojiang2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:31页码:16267-16273 |
| 关键词 | FREQUENCY GENERATION SPECTROSCOPY MELTING-POINT PHOTOELECTRON-SPECTROSCOPY CRYSTAL-STRUCTURES IMIDAZOLIUM INTERFACE GOLD TETRAFLUOROBORATE SUBSTITUENTS CATALYSIS |
| ISSN号 | 2046-2069 |
| 其他题名 | RSC Adv. |
| 中文摘要 | Two imidazolium-based ionic liquids (ILs), i.e. [Bnmim][BF4] (1-benzyl-3-methylimidazolium tetrafluoroborate) and [Bmim][AuCl4] (1-butyl-3-methylimidazolium chloroauric acid), were adsorbed on the outer surface of multi-walled carbon nanotubes (MWCNTs) via a physical method. In order to understand the molecular packing of ILs immobilized on the MWCNTs surfaces, composite samples with different weight ratios of ILs were characterized by using X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). It was found that the rings of imidazolium cations of ILs are nearly parallel to the MWCNTs surfaces, and the packing orientation is determined by the substituent groups on the imidazolium-ring. Both the anions ([BF4](-) and [AuCl4](-)) occupy an adjacent area to the imidazolium cation to form a neutral surface layer. Furthermore, for the immobilized ILs, the melting point (Tm) of [Bmim][AuCl4] rises slightly, while the Tm of [Bnmim][BF4] gets depressed. The molecular rearrangement and the melting point change of the immobilized ILs result from the complex interfacial interactions between the ILs and the MWCNTs surfaces. |
| 英文摘要 | Two imidazolium-based ionic liquids (ILs), i.e. [Bnmim][BF4] (1-benzyl-3-methylimidazolium tetrafluoroborate) and [Bmim][AuCl4] (1-butyl-3-methylimidazolium chloroauric acid), were adsorbed on the outer surface of multi-walled carbon nanotubes (MWCNTs) via a physical method. In order to understand the molecular packing of ILs immobilized on the MWCNTs surfaces, composite samples with different weight ratios of ILs were characterized by using X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). It was found that the rings of imidazolium cations of ILs are nearly parallel to the MWCNTs surfaces, and the packing orientation is determined by the substituent groups on the imidazolium-ring. Both the anions ([BF4](-) and [AuCl4](-)) occupy an adjacent area to the imidazolium cation to form a neutral surface layer. Furthermore, for the immobilized ILs, the melting point (Tm) of [Bmim][AuCl4] rises slightly, while the Tm of [Bnmim][BF4] gets depressed. The molecular rearrangement and the melting point change of the immobilized ILs result from the complex interfacial interactions between the ILs and the MWCNTs surfaces. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | FREQUENCY GENERATION SPECTROSCOPY ; MELTING-POINT ; PHOTOELECTRON-SPECTROSCOPY ; CRYSTAL-STRUCTURES ; IMIDAZOLIUM ; INTERFACE ; GOLD ; TETRAFLUOROBORATE ; SUBSTITUENTS ; CATALYSIS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000334681800055 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11047]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Cuifang,Ren, Baozeng,Song, Yuting,et al. Immobilization and molecular rearrangement of ionic liquids on the surface of carbon nanotubes[J]. RSC ADVANCES,2014,4(31):16267-16273. |
| APA | Zhao, Cuifang.,Ren, Baozeng.,Song, Yuting.,Zhang, Junling.,Wei, Lingchao.,...&Zhang, Suojiang.(2014).Immobilization and molecular rearrangement of ionic liquids on the surface of carbon nanotubes.RSC ADVANCES,4(31),16267-16273. |
| MLA | Zhao, Cuifang,et al."Immobilization and molecular rearrangement of ionic liquids on the surface of carbon nanotubes".RSC ADVANCES 4.31(2014):16267-16273. |
入库方式： OAI收割
来源：过程工程研究所
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