Catalysts, Kinetics, and Reactive Distillation for Methyl Acetate Synthesis
文献类型：期刊论文
| 作者 | Zuo, Cuncun1; Pan, Langsheng1; Cao, Shasha2; Li, Chunshan2; Zhang, Suojiang2 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2014-07-02 |
| 卷号 | 53期号:26页码:10540-10548 |
| 关键词 | ION-EXCHANGE-RESINS ACETIC-ACID HYDROLYSIS REACTION PROPIONIC-ACID N-BUTANOL ESTERIFICATION COLUMN PREDICTION SIMULATION PACKINGS |
| ISSN号 | 0888-5885 |
| 其他题名 | Ind. Eng. Chem. Res. |
| 中文摘要 | Two novel acidic cation-exchange resins, namely, NKC-9 and D072, were first developed to catalyze the esterification of acetic acid with methanol. Kinetics of methyl acetate synthesis are determined by the experiments in a batch reactor at temperatures from 45 to 60 degrees C under atmospheric pressure, with molar ratio of reactants (theta(Bo) = n(methanol):n(acetic acid)) from 0.8 to 1.3. The kinetic data are correlated with the Q-H, E-R, and LHHW and pseudohomogeneous (P-H) models. Then, the reactive distillation process for methyl acetate synthesis is simulated by the Aspen Plus process simulator. Lifetime evaluation of NKC-9 was carried out to study the conversion rate of acetic acid and selectivity of methyl acetate during the long-period running in the fixed-bed reactor. Finally, a series of characterizations such as Fourier transform infrared spectroscopy, X-ray diffraction, and polarizing microscopy were performed to investigate the structure and properties of NKC-9. |
| 英文摘要 | Two novel acidic cation-exchange resins, namely, NKC-9 and D072, were first developed to catalyze the esterification of acetic acid with methanol. Kinetics of methyl acetate synthesis are determined by the experiments in a batch reactor at temperatures from 45 to 60 degrees C under atmospheric pressure, with molar ratio of reactants (theta(Bo) = n(methanol):n(acetic acid)) from 0.8 to 1.3. The kinetic data are correlated with the Q-H, E-R, and LHHW and pseudohomogeneous (P-H) models. Then, the reactive distillation process for methyl acetate synthesis is simulated by the Aspen Plus process simulator. Lifetime evaluation of NKC-9 was carried out to study the conversion rate of acetic acid and selectivity of methyl acetate during the long-period running in the fixed-bed reactor. Finally, a series of characterizations such as Fourier transform infrared spectroscopy, X-ray diffraction, and polarizing microscopy were performed to investigate the structure and properties of NKC-9. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | ION-EXCHANGE-RESINS ; ACETIC-ACID ; HYDROLYSIS REACTION ; PROPIONIC-ACID ; N-BUTANOL ; ESTERIFICATION ; COLUMN ; PREDICTION ; SIMULATION ; PACKINGS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000338693500004 |
| 公开日期 | 2014-08-28 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11063]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Xiangtan Univ, Sch Chem Engn, Xiangtan 411105, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zuo, Cuncun,Pan, Langsheng,Cao, Shasha,et al. Catalysts, Kinetics, and Reactive Distillation for Methyl Acetate Synthesis[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2014,53(26):10540-10548. |
| APA | Zuo, Cuncun,Pan, Langsheng,Cao, Shasha,Li, Chunshan,&Zhang, Suojiang.(2014).Catalysts, Kinetics, and Reactive Distillation for Methyl Acetate Synthesis.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,53(26),10540-10548. |
| MLA | Zuo, Cuncun,et al."Catalysts, Kinetics, and Reactive Distillation for Methyl Acetate Synthesis".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 53.26(2014):10540-10548. |
入库方式： OAI收割
来源：过程工程研究所
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