Phase transfer-based synthesis of HgS nanocrystals
文献类型：期刊论文
| 作者 | Han, Lin1,2; Hou, Pengfei2,3; Feng, Yan2; Liu, Hui2; Li, Jianling3; Peng, Zhijian1; Yang, Jun2 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2014-08-21 |
| 卷号 | 43期号:31页码:11981-11987 |
| 关键词 | GOLD NANOPARTICLES CLUSTER MOLECULES MERCURY SULFIDE NOBLE-METALS GROWTH NANOCOMPOSITES NANORODS HETERODIMERS CORE DOTS |
| ISSN号 | 1477-9226 |
| 其他题名 | Dalton Trans. |
| 中文摘要 | Phase transfer techniques possess remarkable advantages for the synthesis of inorganic nanomaterials. In contrast to the abundant reports on the preparation of noble metal nanoparticles using phase transfer, the number of semiconductor nanocrystals syntheses based on phase transfer techniques is still limited. Herein, we report a systematic study of the phase transfer-based synthesis of HgS nanocrystals, including the tuning of their morphology/shape by either solvent choice or temperature. This strategy involves the transfer of Hg(II) ions from aqueous solution to toluene, oleic acid or oleylamine and subsequent sulfidation at room or elevated temperature. Furthermore, we have extended this phase-transfer based strategy to the fabrication of HgS-Au nanocomposites. The studies in this work might provide a facile route for producing HgS nanocrystals with desirable properties and offer an effective strategy to investigate the influence of the morphology of HgS on the physical/chemical properties of various HgS-based materials. |
| 英文摘要 | Phase transfer techniques possess remarkable advantages for the synthesis of inorganic nanomaterials. In contrast to the abundant reports on the preparation of noble metal nanoparticles using phase transfer, the number of semiconductor nanocrystals syntheses based on phase transfer techniques is still limited. Herein, we report a systematic study of the phase transfer-based synthesis of HgS nanocrystals, including the tuning of their morphology/shape by either solvent choice or temperature. This strategy involves the transfer of Hg(II) ions from aqueous solution to toluene, oleic acid or oleylamine and subsequent sulfidation at room or elevated temperature. Furthermore, we have extended this phase-transfer based strategy to the fabrication of HgS-Au nanocomposites. The studies in this work might provide a facile route for producing HgS nanocrystals with desirable properties and offer an effective strategy to investigate the influence of the morphology of HgS on the physical/chemical properties of various HgS-based materials. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | GOLD NANOPARTICLES ; CLUSTER MOLECULES ; MERCURY SULFIDE ; NOBLE-METALS ; GROWTH ; NANOCOMPOSITES ; NANORODS ; HETERODIMERS ; CORE ; DOTS |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000339862400024 |
| 公开日期 | 2014-08-29 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11332]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.China Univ Geosci, Sch Engn & Technol, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Lin,Hou, Pengfei,Feng, Yan,et al. Phase transfer-based synthesis of HgS nanocrystals[J]. DALTON TRANSACTIONS,2014,43(31):11981-11987. |
| APA | Han, Lin.,Hou, Pengfei.,Feng, Yan.,Liu, Hui.,Li, Jianling.,...&Yang, Jun.(2014).Phase transfer-based synthesis of HgS nanocrystals.DALTON TRANSACTIONS,43(31),11981-11987. |
| MLA | Han, Lin,et al."Phase transfer-based synthesis of HgS nanocrystals".DALTON TRANSACTIONS 43.31(2014):11981-11987. |
入库方式： OAI收割
来源：过程工程研究所
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