New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite
文献类型：期刊论文
| 作者 | Liu, Xiao-Ning1; Guo, Wei-Lei1,2; Hou, Chuan-Jin1; Hu, Xiang-Ping2 |
| 刊名 | synthetic communications
 |
| 出版日期 | 2013-10-02 |
| 卷号 | 43期号:19页码:2622-2626 |
| 关键词 | 1 3-Dienylphosphonates diethyl phosphite Pd-catalyzed propargylic substitution |
| ISSN号 | 0039-7911 |
| 产权排序 | 待补充 |
| 通讯作者 | 侯传金 ; 胡向平 |
| 合作状况 | 英 |
| 英文摘要 | an efficient route to the synthesis of 1,3-dienylphosphonates (1) has been developed for the first time by the substitution of propargylic esters (2) to the diethyl phosphite (3) nucleophile in the presence of pd-2(dba)(3)center dot chcl3 (2mol %) and 2,2-bis(diphenylphosphino)-1,1-binaphthyl (4mol%). both the alkyl and aryl 1,3-dienylphosphonates can be prepared from this transformation. supplemental materials are available for this article. go to the publisher's online edition of synthetic communications (r) to view the free supplemental file. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | stereoselective-synthesis ; 1-alkynylphosphonates ; isomerization ; cycloaddition ; phosphonate ; derivatives ; oxide |
| 收录类别 | SCI ; CCR |
| 资助信息 | 2，2 |
| 原文出处 | 2626 |
| 语种 | 英语 |
| WOS记录号 | WOS:000320914200008 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119095]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiao-Ning,Guo, Wei-Lei,Hou, Chuan-Jin,et al. New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite[J]. synthetic communications,2013,43(19):2622-2626. |
| APA | Liu, Xiao-Ning,Guo, Wei-Lei,Hou, Chuan-Jin,&Hu, Xiang-Ping.(2013).New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite.synthetic communications,43(19),2622-2626. |
| MLA | Liu, Xiao-Ning,et al."New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite".synthetic communications 43.19(2013):2622-2626. |
入库方式： OAI收割
来源：大连化学物理研究所
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