Heat capacities and thermodynamic properties of a 3D Cu(II) supramolecular complex
文献类型：期刊论文
| 作者 | Jiao, Cheng-Li1,2; Wang, Shuang1,2; Si, Xiao-Liang1,2; Li, Zhi-Bao1,2; Liu, Shuang1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; Sun, Yu-Jia4; Zhou, Huai-Ying5 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 112期号:3页码:1565-1571 |
| 关键词 | Copper Molar heat capacity Supramolecule TG TMDSC |
| 通讯作者 | 孙立贤 |
| 产权排序 | 待补充 |
| 合作状况 | 英 |
| 英文摘要 | a 3d supramolecule (h3o)(2)[cu(2,6-pdc)(2)]center dot h2o (pdc = pyridinedicarboxylate) has been solvothermally synthesized and characterized by x-ray powder diffraction and ft-ir spectrum. the thermal decomposition characteristics of the complex were investigated by thermogravimetric analysis, which revealed a three-step mass loss process. the low-temperature molar heat capacities of crystalline (h3o)(2)[cu(2,6-pdc)(2)]center dot h2o were measured by temperature-modulated differential scanning calorimetry for the first time. a phenomenon of glass transition was observed. the thermodynamic parameters such as entropy and enthalpy relative to 298.15 k were calculated based on the above molar heat capacity data. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | magnetic-properties ; crystal-structures ; acid ; calorimetry ; frameworks |
| 资助信息 | 1，1 |
| 收录类别 | SCI |
| 原文出处 | 1571 |
| 语种 | 英语 |
| WOS记录号 | WOS:000319358500051 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119136]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 4.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 5.Guilin Univ Elect Technol, Dept Mat Sci & Engn, Guilin 541004, Peoples R China 6.Tokyo Polytech Univ, Ctr Hyper Media Res, Grad Sch Engn, Atsugi, Kanagawa 2430297, Japan |
| 推荐引用方式 GB/T 7714 | Jiao, Cheng-Li,Wang, Shuang,Si, Xiao-Liang,et al. Heat capacities and thermodynamic properties of a 3D Cu(II) supramolecular complex[J]. journal of thermal analysis and calorimetry,2013,112(3):1565-1571. |
| APA | Jiao, Cheng-Li.,Wang, Shuang.,Si, Xiao-Liang.,Li, Zhi-Bao.,Liu, Shuang.,...&Sawada, Yutaka.(2013).Heat capacities and thermodynamic properties of a 3D Cu(II) supramolecular complex.journal of thermal analysis and calorimetry,112(3),1565-1571. |
| MLA | Jiao, Cheng-Li,et al."Heat capacities and thermodynamic properties of a 3D Cu(II) supramolecular complex".journal of thermal analysis and calorimetry 112.3(2013):1565-1571. |
入库方式： OAI收割
来源：大连化学物理研究所
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