Preparation and Application of Core-Shell Structural Carbon Nanotubes-Molecularly Imprinted Composite Material for Determination of Nafcillin in Egg Samples
文献类型：期刊论文
| 作者 | Liu Yui-Xing1; Jian Gui-Qin1; He Xi-Wen1; Chen Lang-Xing1; Zhang Yu-Kui1,2 |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2013-02-01 |
| 卷号 | 41期号:2页码:161-166 |
| 关键词 | Molecularly imprinted polymers Carbon nanotubes Sol-gel Nafcillin Egg |
| 产权排序 | 待补充 |
| 通讯作者 | 陈朗星 |
| 合作状况 | 英 |
| 英文摘要 | a novel composite material of core-shell molecularly imprinted polymers (mips) was prepared by surface imprinting technique in combination with sol-gel process based on carbon nanotubes (cnts) coated with silica. the morphology and structure of the products (cnts@ naf-mips) were characterized by transmission electron microscopy (tem) and fourier transform infrared spectroscopy (ft-ir). the adsorption properties of cnts@ naf-mips were demonstrated by equilibrium rebinding experiments and langmuir analysis. the maximum adsorption capacity and dissociation constant of cnts@ naf-mips were 9.5 mg/g and 56.6 ml/mg respectively. cnts@ naf-mips showed a fast kinetics and reached the equilibrium only 30 min. the feasibility of determination of nafcillin from real samples was testified in spiked egg samples with concentration of 5 and 10 mu g/kg by using the imprinted polymer as the adsorption material. the recoveries of nafcillin were ranged from 61.3% to 84.3% with good accuracy. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | performance liquid-chromatography ; tandem mass-spectrometry ; beta-lactam antibiotics ; polymers ; recognition ; pollutants |
| 收录类别 | SCI |
| 资助信息 | 2，5 |
| 原文出处 | 166 |
| 语种 | 英语 |
| WOS记录号 | WOS:000318392300001 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119161]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Yui-Xing,Jian Gui-Qin,He Xi-Wen,et al. Preparation and Application of Core-Shell Structural Carbon Nanotubes-Molecularly Imprinted Composite Material for Determination of Nafcillin in Egg Samples[J]. chinese journal of analytical chemistry,2013,41(2):161-166. |
| APA | Liu Yui-Xing,Jian Gui-Qin,He Xi-Wen,Chen Lang-Xing,&Zhang Yu-Kui.(2013).Preparation and Application of Core-Shell Structural Carbon Nanotubes-Molecularly Imprinted Composite Material for Determination of Nafcillin in Egg Samples.chinese journal of analytical chemistry,41(2),161-166. |
| MLA | Liu Yui-Xing,et al."Preparation and Application of Core-Shell Structural Carbon Nanotubes-Molecularly Imprinted Composite Material for Determination of Nafcillin in Egg Samples".chinese journal of analytical chemistry 41.2(2013):161-166. |
入库方式： OAI收割
来源：大连化学物理研究所
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