Hydrogenation and cleavage of the C-O bonds in the lignin model compound phenethyl phenyl ether over a nickel-based catalyst
文献类型：期刊论文
| 作者 | Song Qi1,2; Cai Jiaying1,2; Zhang Junjie1,2; Yu Weiqiang1; Wang Feng1; Xu Jie1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2013-04-01 |
| 卷号 | 34期号:4页码:651-658 |
| 关键词 | Lignin model compound Phenethyl phenyl ether Hydrogenation and cleavage Nickel catalyst Aromatic compound |
| 产权排序 | 待补充 |
| 通讯作者 | 王峰 ; 徐杰 |
| 合作状况 | 英 |
| 英文摘要 | phenethyl phenyl ether (ppe) was selected as a typical lignin model compound and hydrogenated and cleaved over two readily accessible nickel-based catalysts, which could be easily separated from the product mixture. the results revealed that the reduction of the nickel catalyst with gaseous hydrogen produced a species capable of achieving higher activity towards c-o-c bond cleavage compared to the ru/c and pd/c catalysts. the selectivity of the c-o-c bond cleavage over the ni/c catalyst was 85%, and higher than the corresponding values in the ru/c (40%) and pd/c (69%) systems. using the carbothermal reduction method for the production of the ni/c-c catalyst, the conversion and selectivity levels reached 99%, with 40% of the benzene rings in ppe being reserved. in comparison, no benzene ring containing products wer observed over the noble metal catalysts. this difference was attributed to the interaction between the carbon support and the nickel nanoparticles. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | ni-based catalysts ; aerobic oxidation ; benzene hydrogenation ; vanadium catalyst ; synthesis gas ; hydrogenolysis ; performance ; pyrolysis ; glycerol ; biomass |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 658 |
| 语种 | 英语 |
| WOS记录号 | WOS:000318750500003 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119162]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song Qi,Cai Jiaying,Zhang Junjie,et al. Hydrogenation and cleavage of the C-O bonds in the lignin model compound phenethyl phenyl ether over a nickel-based catalyst[J]. chinese journal of catalysis,2013,34(4):651-658. |
| APA | Song Qi,Cai Jiaying,Zhang Junjie,Yu Weiqiang,Wang Feng,&Xu Jie.(2013).Hydrogenation and cleavage of the C-O bonds in the lignin model compound phenethyl phenyl ether over a nickel-based catalyst.chinese journal of catalysis,34(4),651-658. |
| MLA | Song Qi,et al."Hydrogenation and cleavage of the C-O bonds in the lignin model compound phenethyl phenyl ether over a nickel-based catalyst".chinese journal of catalysis 34.4(2013):651-658. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。