Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries
文献类型：期刊论文
| 作者 | Liu, Xin1; Wu, Minghao2; Li, Mingrun1; Pan, Xiulian1; Chen, Jian2; Bao, Xinhe1 |
| 刊名 | journal of materials chemistry a
 |
| 出版日期 | 2013 |
| 卷号 | 1期号:33页码:9527-9535 |
| 产权排序 | 待补充 |
| 通讯作者 | 潘秀莲 ; 陈剑 |
| 合作状况 | 英 |
| 英文摘要 | an efficient anode with a superior high-rate capability and stability remains a challenge for development of high performance li-ion batteries. we present a new concept by encapsulating 2 nm-sized sno2 nanocrystals in the channels of carbon nanotubes (sno2-in-cnts). characterization shows that the confined space does not only stabilize the small nanoparticles but also alleviates the stress caused by the large volume change of tin species during the charging-discharging process. in addition, well crystallized graphitic structure of cnts with a positive curvature provides a good contact between sno2 nanoparticles and graphene layers, and excellent electronic conductivity. as a result, sno2-in-cnts as an anode of lithium ion battery exhibit stable cyclability and superior high-rate capability relative to sno2 nanoparticles dispersed on the outer walls of cnts particularly under a high current density. the charge capacity remains about 560 ma h g(-1) after 50 cycles at 50 ma g(-1), and even around 400 ma h g(-1) at 1000 ma g(-1). additionally, the facile preparation method we have developed makes such encapsulates appealing for further optimization and applications. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; energy & fuels ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; energy & fuels ; materials science |
| 关键词[WOS] | lithium secondary batteries ; large-scale synthesis ; tin oxide composites ; high-capacity ; electrochemical performance ; rechargeable batteries ; storage capacity ; nanoparticles ; fabrication ; lithiation |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 9535 |
| 语种 | 英语 |
| WOS记录号 | WOS:000322475600026 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119289]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Adv Rechargeable Batteries Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xin,Wu, Minghao,Li, Mingrun,et al. Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries[J]. journal of materials chemistry a,2013,1(33):9527-9535. |
| APA | Liu, Xin,Wu, Minghao,Li, Mingrun,Pan, Xiulian,Chen, Jian,&Bao, Xinhe.(2013).Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries.journal of materials chemistry a,1(33),9527-9535. |
| MLA | Liu, Xin,et al."Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries".journal of materials chemistry a 1.33(2013):9527-9535. |
入库方式： OAI收割
来源：大连化学物理研究所
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