Temperature-programmed desorption and surface reaction studies of CO on Co2C
文献类型：期刊论文
| 作者 | Pei, Yanpeng1,3; Ding, Yunjie1,2; Zang, Juan1,3; Song, Xiangen1,3; Dong, Wenda1,3; Zhu, Hejun1; Wang, Tao1; Chen, Weimiao1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2013-08-01 |
| 卷号 | 34期号:8页码:1570-1575 |
| 关键词 | Cobalt carbide Passivation layer Carbon monoxide adsorption Hydrogenation Alcohol |
| ISSN号 | 0253-9837 |
| 产权排序 | 待补充 |
| 通讯作者 | 丁云杰 |
| 合作状况 | 英 |
| 英文摘要 | cobalt carbide (co2c) samples were prepared by carburizing co with co at 473 k for in excess of 400 h and were characterized by x-ray diffraction, transmission electron microscopy, co temperature-programmed reduction, co temperature-programmed desorption (co-tpd), and co temperature-programmed surface reaction. the prepared co2c samples were composed of bulk co2c with a surface coo passivation layer. the passivation layer could be removed by reaction with co at 477 k. co desorbing at low temperature in co-tpd experiments likely originated from chemisorbed co. co desorbing at high temperature was likely due to residual co within the co2c crystal lattice. co adsorbed on co2c reacted with h-2 to form alcohol. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | molybdenum carbide catalyst ; linear alpha-alcohols ; co/ac catalysts ; cobalt ; syngas ; dehydrogenation ; hydrogenation ; nitrides ; gas ; no |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 1575 |
| 语种 | 英语 |
| WOS记录号 | WOS:000323239600013 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119295]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pei, Yanpeng,Ding, Yunjie,Zang, Juan,et al. Temperature-programmed desorption and surface reaction studies of CO on Co2C[J]. chinese journal of catalysis,2013,34(8):1570-1575. |
| APA | Pei, Yanpeng.,Ding, Yunjie.,Zang, Juan.,Song, Xiangen.,Dong, Wenda.,...&Chen, Weimiao.(2013).Temperature-programmed desorption and surface reaction studies of CO on Co2C.chinese journal of catalysis,34(8),1570-1575. |
| MLA | Pei, Yanpeng,et al."Temperature-programmed desorption and surface reaction studies of CO on Co2C".chinese journal of catalysis 34.8(2013):1570-1575. |
入库方式： OAI收割
来源：大连化学物理研究所
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