Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water
文献类型：期刊论文
| 作者 | Zhou, Lipeng1; Yu, Wenjun1; Wu, Lin1; Liu, Zhen1; Chen, Haijun1; Yang, Xiaomei1; Su, Yunlai1; Xu, Jie2 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2013-01-31 |
| 卷号 | 451页码:137-143 |
| 关键词 | Au/Nay Oxidation Alcohol Carboxylic acid |
| 产权排序 | 待补充 |
| 通讯作者 | 杨晓梅 |
| 合作状况 | 英 |
| 英文摘要 | au/nay was prepared by deposition-precipitation (dp) method using haucl4 as gold source. the samples were characterized by x-ray diffraction, n-2 adsorption, transmission electron microscopy and inductively coupled plasma atomic emission spectrometry. it was found that the adjustment of the surface acidity of nay, the ph and concentration of haucl4 solution, and the temperature and time for dp affected the particle size, the loading and the morphology of au on nay. the catalytic performance of au/nay was studied in the oxidation of alcohols to the corresponding carboxylic acids with molecular oxygen as oxidant under basic conditions. about 100% conversion of benzyl alcohol with 95.2% isolated yield of benzoic acid was obtained at the reaction temperature of 80 degrees c for 8 h. the catalyst was recycled for four times without loss of catalytic activity. in addition, the catalyst worked well for the catalytic oxidation of various alcohols including aromatic and aliphatic alcohols to the corresponding carboxyl acids. (c) 2012 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | selective oxidation ; aerobic oxidation ; co oxidation ; nanoparticle catalysts ; carbon-monoxide ; nano-gold ; temperature ; aldehydes ; zeolites ; ph |
| 收录类别 | SCI |
| 资助信息 | 2，8 |
| 原文出处 | 143 |
| 语种 | 英语 |
| WOS记录号 | WOS:000315069200019 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119342]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Lipeng,Yu, Wenjun,Wu, Lin,et al. Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water[J]. applied catalysis a-general,2013,451:137-143. |
| APA | Zhou, Lipeng.,Yu, Wenjun.,Wu, Lin.,Liu, Zhen.,Chen, Haijun.,...&Xu, Jie.(2013).Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water.applied catalysis a-general,451,137-143. |
| MLA | Zhou, Lipeng,et al."Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water".applied catalysis a-general 451(2013):137-143. |
入库方式： OAI收割
来源：大连化学物理研究所
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