Transalkylation of Phenol with Cumene on Zeolite Catalysts
文献类型：期刊论文
| 作者 | Huang, Shengjun1; Zhang, Shuang1; Yu, Lili1,2; Liu, Zhenni1; Xin, Wenjie1; Xie, Sujuan1; Xu, Longya1 |
| 刊名 | industrial & engineering chemistry research
 |
| 出版日期 | 2013-08-14 |
| 卷号 | 52期号:32页码:10996-11000 |
| 产权排序 | 待补充 |
| 通讯作者 | 徐龙伢 |
| 合作状况 | 英 |
| 英文摘要 | liquid-phase transalkylation of phenol with cumene was studied over various zeolites. among the evaluated catalysts, zsm-5 zeolites showed higher activities (ca. 50% phenol conversion) and usage efficiencies of isopropyl groups (ca. 80%) at 200 degrees c and 1.5 mpa. the higher catalytic performances of zsm-5 zeolites are closely related to their channel structure and moderate cumene uptake capacities. it has been shown that the activities are related to the strong acidity of zsm-5 zeolites. the passivation of external acid sites on zsm-5 zeolite enhances the selectivity for para-isopropylphenol. |
| WOS标题词 | science & technology ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | engineering, chemical |
| 研究领域[WOS] | engineering |
| 关键词[WOS] | al-mcm-41 molecular-sieves ; vapor-phase isopropylation ; zsm-5 ; alkylation ; acidity |
| 收录类别 | SCI |
| 资助信息 | 1,1 |
| 原文出处 | 11000 |
| 语种 | 英语 |
| WOS记录号 | WOS:000323240900014 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119436]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Shengjun,Zhang, Shuang,Yu, Lili,et al. Transalkylation of Phenol with Cumene on Zeolite Catalysts[J]. industrial & engineering chemistry research,2013,52(32):10996-11000. |
| APA | Huang, Shengjun.,Zhang, Shuang.,Yu, Lili.,Liu, Zhenni.,Xin, Wenjie.,...&Xu, Longya.(2013).Transalkylation of Phenol with Cumene on Zeolite Catalysts.industrial & engineering chemistry research,52(32),10996-11000. |
| MLA | Huang, Shengjun,et al."Transalkylation of Phenol with Cumene on Zeolite Catalysts".industrial & engineering chemistry research 52.32(2013):10996-11000. |
入库方式： OAI收割
来源：大连化学物理研究所
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