中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate

文献类型:期刊论文

作者Xue, Huifu1; Huang, Xiumin1; Ditzel, Evert2; Zhan, Ensheng1; Ma, Meng1; Shen, Wenjie1
刊名chinese journal of catalysis
出版日期2013-08-01
卷号34期号:8页码:1496-1503
关键词H-mordenite Dimethyl ether Carbonylation Crystal size Coking
产权排序待补充
通讯作者申文杰
合作状况
英文摘要as compared to conventional micrometer-sized mordenite particles, nanometer-sized mordenite gave a much higher activity and better stability in dimethyl ether carbonylation to methyl acetate by suppressing the deposition of hard coke. a structural analysis revealed that intra-crystalline diffusion limitation of the reactants and products to and from the active sites inside the channels was greatly decreased by reducing the zeolite size to the nanometer size. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
学科主题物理化学
类目[WOS]chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]selective carbonylation ; zeolite deactivation ; zsm-5 nanocrystals ; crystallite size ; acidic zeolites ; single-crystals ; coke formation ; h-mordenite ; methanol ; catalyst
收录类别SCI
资助信息1,1
原文出处1503
语种英语
WOS记录号WOS:000323239600004
公开日期2014-09-11
源URL[http://159.226.238.44/handle/321008/119451]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England
推荐引用方式
GB/T 7714
Xue, Huifu,Huang, Xiumin,Ditzel, Evert,et al. Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate[J]. chinese journal of catalysis,2013,34(8):1496-1503.
APA Xue, Huifu,Huang, Xiumin,Ditzel, Evert,Zhan, Ensheng,Ma, Meng,&Shen, Wenjie.(2013).Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate.chinese journal of catalysis,34(8),1496-1503.
MLA Xue, Huifu,et al."Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate".chinese journal of catalysis 34.8(2013):1496-1503.

入库方式: OAI收割

来源:大连化学物理研究所

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