Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate
文献类型:期刊论文
作者 | Xue, Huifu1; Huang, Xiumin1; Ditzel, Evert2; Zhan, Ensheng1; Ma, Meng1; Shen, Wenjie1 |
刊名 | chinese journal of catalysis
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出版日期 | 2013-08-01 |
卷号 | 34期号:8页码:1496-1503 |
关键词 | H-mordenite Dimethyl ether Carbonylation Crystal size Coking |
产权排序 | 待补充 |
通讯作者 | 申文杰 |
合作状况 | 英 |
英文摘要 | as compared to conventional micrometer-sized mordenite particles, nanometer-sized mordenite gave a much higher activity and better stability in dimethyl ether carbonylation to methyl acetate by suppressing the deposition of hard coke. a structural analysis revealed that intra-crystalline diffusion limitation of the reactants and products to and from the active sites inside the channels was greatly decreased by reducing the zeolite size to the nanometer size. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
学科主题 | 物理化学 |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | selective carbonylation ; zeolite deactivation ; zsm-5 nanocrystals ; crystallite size ; acidic zeolites ; single-crystals ; coke formation ; h-mordenite ; methanol ; catalyst |
收录类别 | SCI |
资助信息 | 1,1 |
原文出处 | 1503 |
语种 | 英语 |
WOS记录号 | WOS:000323239600004 |
公开日期 | 2014-09-11 |
源URL | [http://159.226.238.44/handle/321008/119451] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England |
推荐引用方式 GB/T 7714 | Xue, Huifu,Huang, Xiumin,Ditzel, Evert,et al. Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate[J]. chinese journal of catalysis,2013,34(8):1496-1503. |
APA | Xue, Huifu,Huang, Xiumin,Ditzel, Evert,Zhan, Ensheng,Ma, Meng,&Shen, Wenjie.(2013).Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate.chinese journal of catalysis,34(8),1496-1503. |
MLA | Xue, Huifu,et al."Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate".chinese journal of catalysis 34.8(2013):1496-1503. |
入库方式: OAI收割
来源:大连化学物理研究所
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