Direct synthesis of phenol from benzene catalyzed by multi-V-POMs complex
文献类型：期刊论文
| 作者 | Yang, Hua1,2,3; Wu, Qing4; Li, Jun1,2; Dai, Wen1,2,3; Zhang, Hengyun1,2; Lu, Dan5; Gao, Shuang1,2; You, Wansheng4 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2013-04-24 |
| 卷号 | 457页码:21-25 |
| 关键词 | Heteropolymolybdates Vanadium-containing cation Benzene Phenol H2O2 |
| 产权排序 | 待补充 |
| 通讯作者 | 高爽 ; wansheng you |
| 合作状况 | 英 |
| 英文摘要 | a novel catalyst, [mo2v2o9(bpy)(6)][pmo11vo40], was synthesized by the self-assembling of [pmo11vo40](4-) and [mo2v2o9(bpy)(6)](4+) unit and characterized by elemental analyses, tg, ir, x-ray powder diffraction and x-ray single crystal diffraction. [mo2v2o9(bpy)(6)][pmo11vo40] with multi-isolated active sites showed good catalytic activities for hydroxylation of benzene to phenol. a high yield of phenol (25.5%) with selectivity to phenol of 90.7% was obtained using h2o2 as oxidant. the catalyst can be recycled for 5 times while its structure was unchanged and its catalytic activity was maintained. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | vanadium-substituted heteropolymolybdates ; hydrogen-peroxide ; selective hydroxylation ; direct oxidation ; acid ; oxygen ; oxide ; epoxidation ; metals ; system |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 25 |
| 语种 | 英语 |
| WOS记录号 | WOS:000319791000003 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119504]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, DICP, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Liaoning Normal Univ, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China 5.Yanshan Univ, Liren Coll, Qinhuangdao 066004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Hua,Wu, Qing,Li, Jun,et al. Direct synthesis of phenol from benzene catalyzed by multi-V-POMs complex[J]. applied catalysis a-general,2013,457:21-25. |
| APA | Yang, Hua.,Wu, Qing.,Li, Jun.,Dai, Wen.,Zhang, Hengyun.,...&You, Wansheng.(2013).Direct synthesis of phenol from benzene catalyzed by multi-V-POMs complex.applied catalysis a-general,457,21-25. |
| MLA | Yang, Hua,et al."Direct synthesis of phenol from benzene catalyzed by multi-V-POMs complex".applied catalysis a-general 457(2013):21-25. |
入库方式： OAI收割
来源：大连化学物理研究所
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