The improved reactivity of manganese catalysts by Ag in catalytic oxidation of toluene
文献类型：期刊论文
| 作者 | Qu, Zhenping1; Bu, Yibin1; Qin, Yuan1; Wang, Yi1; Fu, Qiang2 |
| 刊名 | applied catalysis b-environmental
 |
| 出版日期 | 2013-03-27 |
| 卷号 | 132页码:353-362 |
| 关键词 | Toluene oxidation Ag-Mn/SBA-15 Redox properties Lattice oxygen Interaction |
| 产权排序 | 待补充 |
| 通讯作者 | zhenping qu |
| 合作状况 | 英 |
| 英文摘要 | the effects of ag on mn/sba-15 catalysts have been investigated in the toluene catalytic oxidation. the reactivity of catalysts is related closely to the ag/mn molar ratio, and the sample with 1:3 of ag/mn molar ratio exhibits the highest reactivity for toluene oxidation, with a complete conversion at 260 degrees c. based on the characterization results, it is found that ag enters into mno2 phase, and the ag1.8mn8o16 mixed phase forms. meanwhile ag leads to parts of mno2 being transformed into mn2o3. the ag/mn molar ratio has a strong influence on the molar ratio of the surface mn4+ to mn3+ and surface adsorbed oxygen (o-ads) to lattice oxygen (o-latt) through the interaction between silver and mnox. the coexistence of mno2, mn2o3, ag1.8mn8o16, and the strong interactions between ag and mn species exhibit a good synergetic interaction, which promotes the reducibility of catalysts and the formation of abundant active lattice oxygen, thus increasing the catalytic activity of toluene oxidation. and the formation of intermediate benzaldehyde should be closely link with the lattice oxygen of the mn based catalyst. (c) 2012 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; engineering, environmental ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | volatile organic-compounds ; oxide catalysts ; lattice oxygen ; photocatalytic oxidation ; low-temperatures ; ch4 oxidation ; co oxidation ; gas-phase ; combustion ; silver |
| 收录类别 | SCI |
| 资助信息 | 2，5 |
| 原文出处 | 362 |
| 语种 | 英语 |
| WOS记录号 | WOS:000315369700038 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119512]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qu, Zhenping,Bu, Yibin,Qin, Yuan,et al. The improved reactivity of manganese catalysts by Ag in catalytic oxidation of toluene[J]. applied catalysis b-environmental,2013,132:353-362. |
| APA | Qu, Zhenping,Bu, Yibin,Qin, Yuan,Wang, Yi,&Fu, Qiang.(2013).The improved reactivity of manganese catalysts by Ag in catalytic oxidation of toluene.applied catalysis b-environmental,132,353-362. |
| MLA | Qu, Zhenping,et al."The improved reactivity of manganese catalysts by Ag in catalytic oxidation of toluene".applied catalysis b-environmental 132(2013):353-362. |
入库方式： OAI收割
来源：大连化学物理研究所
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