Preparation of polyhedral oligomeric silsesquioxane based hybrid monoliths by ring-opening polymerization for capillary LC and CEC
文献类型：期刊论文
| 作者 | Lin, Hui1,2; Zhang, Zhenbin1,2; Dong, Jing1; Liu, Zhongshan1,2; Ou, Junjie1; Zou, Hanfa1 |
| 刊名 | journal of separation science
 |
| 出版日期 | 2013-09-01 |
| 卷号 | 36期号:17页码:2819-2825 |
| 关键词 | Chromatographic separation Hybrid monoliths Polyhedral oligomeric silsesquioxane POSS Ring-opening polymerization |
| ISSN号 | 1615-9306 |
| 产权排序 | 待补充 |
| 通讯作者 | 邹汉法 ; 欧俊杰 |
| 合作状况 | 英 |
| 英文摘要 | a new organic-inorganic hybrid monolith was prepared by the ring-opening polymerization of octaglycidyldimethylsilyl polyhedral oligomeric silsesquioxane (poss) with 1,4-butanediamine (bda) using 1-propanol, 1,4-butanediol, and peg 10 000 as a porogenic system. benefiting from the moderate phase separation process, the resulting poly(poss-co-bda) hybrid monolith possessed a uniform microstructure and exhibited excellent performance in chromatographic applications. neutral, acidic, and basic compounds were successfully separated on the hybrid monolith in capillary lc (clc), and high column efficiencies were achieved in all of the separations. in addition, as the amino groups could generate a strong eof, the hybrid monolith was also applied in cec for the separation of neutral and polar compounds, and a satisfactory performance was obtained. these results demonstrate that the poly(poss-co-bda) hybrid monolith is a good separation media in chromatographic separations of various types of compounds by both clc and cec. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | one-pot process ; liquid-chromatography ; electrochromatography ; columns ; proteins ; facile ; flow |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 2825 |
| 语种 | 英语 |
| WOS记录号 | WOS:000323891300013 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119566]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Natl Chromatog R&A Ctr, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Hui,Zhang, Zhenbin,Dong, Jing,et al. Preparation of polyhedral oligomeric silsesquioxane based hybrid monoliths by ring-opening polymerization for capillary LC and CEC[J]. journal of separation science,2013,36(17):2819-2825. |
| APA | Lin, Hui,Zhang, Zhenbin,Dong, Jing,Liu, Zhongshan,Ou, Junjie,&Zou, Hanfa.(2013).Preparation of polyhedral oligomeric silsesquioxane based hybrid monoliths by ring-opening polymerization for capillary LC and CEC.journal of separation science,36(17),2819-2825. |
| MLA | Lin, Hui,et al."Preparation of polyhedral oligomeric silsesquioxane based hybrid monoliths by ring-opening polymerization for capillary LC and CEC".journal of separation science 36.17(2013):2819-2825. |
入库方式： OAI收割
来源：大连化学物理研究所
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