Conversion of Glucose to 5-Hydroxymethylfurfural Catalyzed by Metal Halide in N,N-Dimethylacetamide
文献类型：期刊论文
| 作者 | Ren, Qiuhe1,2,3; Huang, Yizheng1,2; Ma, Hong1,2; Wang, Feng1,2; Gao, Jin1,2; Xu, Jie1,2 |
| 刊名 | bioresources
 |
| 出版日期 | 2013 |
| 卷号 | 8期号:2页码:1563-1572 |
| 关键词 | Glucose Dehydration Metal halide 5-Hydroxymethylfurfural |
| 产权排序 | 待补充 |
| 通讯作者 | 徐杰 |
| 合作状况 | 英 |
| 英文摘要 | a simple strategy is reported for catalytic conversion of glucose to 5-hydroxymethylfurfural (hmf) over all(3) in n,n-dimethylacetamide (dmac). when the reaction was conducted in dmac at 120 degrees c for 15 min over all(3) catalyst, hmf was obtained with a yield of 52%. the reaction course was monitored by c-13 nmr spectroscopy and hplc analysis. the results suggest that all(3) catalyzes the three consecutive reactions consisting of mutarotation of alpha-glucopyranose to beta-glucopyranose, isomerization of glucose to fructose, and dehydration of fructose to hmf. |
| WOS标题词 | science & technology ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | materials science, paper & wood |
| 研究领域[WOS] | materials science |
| 关键词[WOS] | lignocellulosic biomass ; ionic liquid ; solid acid ; chemicals ; chloride ; fuels ; water ; hmf ; fructose ; solvents |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 1572 |
| 语种 | 英语 |
| WOS记录号 | WOS:000315386400008 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119580]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Qiuhe,Huang, Yizheng,Ma, Hong,et al. Conversion of Glucose to 5-Hydroxymethylfurfural Catalyzed by Metal Halide in N,N-Dimethylacetamide[J]. bioresources,2013,8(2):1563-1572. |
| APA | Ren, Qiuhe,Huang, Yizheng,Ma, Hong,Wang, Feng,Gao, Jin,&Xu, Jie.(2013).Conversion of Glucose to 5-Hydroxymethylfurfural Catalyzed by Metal Halide in N,N-Dimethylacetamide.bioresources,8(2),1563-1572. |
| MLA | Ren, Qiuhe,et al."Conversion of Glucose to 5-Hydroxymethylfurfural Catalyzed by Metal Halide in N,N-Dimethylacetamide".bioresources 8.2(2013):1563-1572. |
入库方式： OAI收割
来源：大连化学物理研究所
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