Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones
文献类型：期刊论文
| 作者 | Du, Wangming1; Wu, Ping1; Wang, Qingfu1; Yu, Zhengkun1,2 |
| 刊名 | organometallics
 |
| 出版日期 | 2013-05-27 |
| 卷号 | 32期号:10页码:3083-3090 |
| 产权排序 | 待补充 |
| 通讯作者 | 余正坤 |
| 合作状况 | 英 |
| 英文摘要 | air- and moisture-stable ruthenium(h) complexes bearing a unsymmetrical 2-(benzimidazol-2-yl)-6-(benzotriazol-1-yl)pyridine ligand were synthesized and structurally characterized by nmr analysis and xray crystallographic determinations. these complexes have exhibited excellent catalytic activity in the transfer hydrogenation of ketones in refluxing 2-propanol, reaching final tofs up to 176400 h(-1). the corresponding ruh complex was isolated and is proposed as the catalytically active species by controlled experiments. the high catalytic activity of the ru(ii) the complex catalysts is attributed to the hemilabile unsymmetrical coordinating environment around the central metal atom in the complexes and presence of a convertible benzimidazolyl nh functionality in the ligand. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric transfer hydrogenation ; pyrazolyl-imidazolyl ligand ; carbonyl-compounds ; efficient catalysts ; iron(ii) complexes ; h-2 hydrogenation ; metal-catalysts ; hydride complex ; spin-crossover ; reduction |
| 收录类别 | SCI ; IC ; CCR |
| 资助信息 | 1，1 |
| 原文出处 | 3090 |
| 语种 | 英语 |
| WOS记录号 | WOS:000319650300027 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119671]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Wangming,Wu, Ping,Wang, Qingfu,et al. Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones[J]. organometallics,2013,32(10):3083-3090. |
| APA | Du, Wangming,Wu, Ping,Wang, Qingfu,&Yu, Zhengkun.(2013).Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones.organometallics,32(10),3083-3090. |
| MLA | Du, Wangming,et al."Ruthenium(II) Complex Catalysts Bearing a Pyridyl-Based Benzimidazolyl-Benzotriazolyl Ligand for Transfer Hydrogenation of Ketones".organometallics 32.10(2013):3083-3090. |
入库方式： OAI收割
来源：大连化学物理研究所
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