Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation
文献类型：期刊论文
| 作者 | Sha, Sha1,2,3; Yang, Hua1,2; Li, Jun1,2; Zhuang, Changfu1,2; Gao, Shuang1,2; Liu, Shuxia3 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2014-01-05 |
| 卷号 | 43页码:146-150 |
| 关键词 | MOFs Oxygen Epoxidation Olefin |
| 产权排序 | 待补充 |
| 通讯作者 | 高爽 ; shuxia liu |
| 合作状况 | 英 |
| 英文摘要 | an 8-connected, linear trinuclear cluster-based microporous metal organic framework (nh4)(2)[co-3(ina)(bdc)(3)(hcoo)] (denoted as co(3)inabdc(3), ina = isonicotinate and bdc = 1,4-benzenedicarboxylate, ccdc is 935147) had been successfully synthesized by a facile hydrothermal synthesis method. the compound was extended through bdc linkers breadthwise and ina linkers lengthways to the highly-connected framework. the co(3)inabdc(3) was characterized through ft-ir, n-2 adsorption, xrd, tga and sem, and its characteristic structure was elucidated by single crystal x-ray diffraction. using o-2 as oxidant, the co(3)inabdc(3) was investigated as a good performed heterogeneous catalytic material for cydooctene epoxidation. an extremely high turnover frequency (1370 h(-1)) for epoxycyclooctane was achieved, and co(3)inabdc(3) exhibited excellent stabilities in 5 recycles without any loss of its catalytic performance. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | molecular-oxygen ; hydrogen-peroxide ; complex ; alkenes ; oxidation ; dioxygen ; styrene |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 150 |
| 语种 | 英语 |
| WOS记录号 | WOS:000328527000032 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119742]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sha, Sha,Yang, Hua,Li, Jun,et al. Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation[J]. catalysis communications,2014,43:146-150. |
| APA | Sha, Sha,Yang, Hua,Li, Jun,Zhuang, Changfu,Gao, Shuang,&Liu, Shuxia.(2014).Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation.catalysis communications,43,146-150. |
| MLA | Sha, Sha,et al."Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation".catalysis communications 43(2014):146-150. |
入库方式： OAI收割
来源：大连化学物理研究所
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