Hierarchically porous carbons with partially graphitized structures for high rate supercapacitors
文献类型:期刊论文
作者 | Jiang, Liang1,2; Yan, Jingwang1,2; Xue, Rong1,2; Hao, Lixing1,2; Jiang, Lei1,3,4; Sun, Gongquan1,2; Yi, Baolian1,2 |
刊名 | journal of materials science |
出版日期 | 2014 |
卷号 | 49期号:1页码:363-370 |
ISSN号 | 0022-2461 |
通讯作者 | 阎景旺 |
产权排序 | 待补充 |
合作状况 | 英 |
英文摘要 | partially graphitized hierarchically porous carbons (denoted as ghpcs) were prepared by using ordered mesoporous nickel oxide as template. the mesoporous nickel oxide, which is different from the inert template such as mesoporous silica sba-15, plays an important role in the synthesis of the carbons with partially graphitized nanostructures at high temperature. x-ray diffraction, transmission electron microscopy and nitrogen adsorption were employed to characterize the structure of ghpcs. it is shown that the ghpc obtained by calcinating the precursor at 700 degrees c has a hierarchically porous structure with the pore size distributions at 8 and 30 nm. partially graphitized structure leads to the high electrical conductivity of ghpcs. the ghpc prepared at 700 degrees c (ghpc700) shows outstanding high rate performance. its specific capacitance reaches 91 f g(-1) at a potential scan rate of 500 mv s(-1). meanwhile the specific capacitance for the ghpc prepared at 600 degrees c (ghpc600) is only 46 f g(-1) at the same scan rate. synergistic effect of the efficient ion transport in hierarchically porous structure and the high electrical conductivity owing to the partially graphitic structure is contributed to the attractive electrochemical performance of ghpc700. |
学科主题 | 物理化学 |
WOS标题词 | science & technology ; technology |
类目[WOS] | materials science, multidisciplinary |
研究领域[WOS] | materials science |
关键词[WOS] | ordered mesoporous carbons ; capacitive energy-storage ; electrochemical performance ; catalytic graphitization ; silica ; oxide ; copolymer ; impedance ; triblock |
资助信息 | 1,1 |
收录类别 | SCI |
原文出处 | 370 |
语种 | 英语 |
WOS记录号 | WOS:000328260200038 |
公开日期 | 2014-09-11 |
源URL | [http://159.226.238.44/handle/321008/119761] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 4.Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Liang,Yan, Jingwang,Xue, Rong,et al. Hierarchically porous carbons with partially graphitized structures for high rate supercapacitors[J]. journal of materials science,2014,49(1):363-370. |
APA | Jiang, Liang.,Yan, Jingwang.,Xue, Rong.,Hao, Lixing.,Jiang, Lei.,...&Yi, Baolian.(2014).Hierarchically porous carbons with partially graphitized structures for high rate supercapacitors.journal of materials science,49(1),363-370. |
MLA | Jiang, Liang,et al."Hierarchically porous carbons with partially graphitized structures for high rate supercapacitors".journal of materials science 49.1(2014):363-370. |
入库方式: OAI收割
来源:大连化学物理研究所
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