Ethylene glycol adjusted nanorod hematite film for active photoelectrochemical water splitting
文献类型：期刊论文
| 作者 | Fu, Li1,2; Yu, Hongmei1; Li, Yongkun1,2; Zhang, Changkun1,2; Wang, Xunying1,2; Shao, Zhigang1; Yi, Baolian1 |
| 刊名 | physical chemistry chemical physics
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:9页码:4284-4290 |
| 产权排序 | 待补充 |
| 通讯作者 | 俞红梅 ; 邵志刚 |
| 合作状况 | 英 |
| 英文摘要 | we reported a facile adjusted method for the synthesis of high surface area nanorod hematite film as a photoanode for application in water splitting. crystalline hematite nanorods (eg-alpha-fe2o3) are fabricated by electrodeposition in fe2+ precursor solution with the addition of ethylene glycol (eg) and followed by annealing at 450 degrees c. the nanorod hematite film fabricated by the modified electrodeposition approach exhibits a more uncompact structure than alpha-fe2o3 obtained by directly electrodepositing on the fto substrate. the optical and structural characteristics of the obtained film are also tested. the results infer that eg can tune the morphology of hematite and improve the photoabsorption in the visible light region due to its inducement of one-dimensional growth of crystal hematite. it also enhances the photoresponse activity of hematite in water splitting by improving the activities at the semiconductor/solution interface. the photocurrent density of eg-alpha-fe2o3 nanorods increased to 0.24 ma cm(-2) at 1.4 v vs. rhe in 1 m koh (ph = 13.6), almost 5 times higher than the original alpha-fe2o3 (0.05 ma cm(-2), measured under the same conditions). |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | solar-energy ; photoanodes ; photoelectrolysis ; photocatalysis ; catalysts ; progress ; arrays ; fe2o3 ; cells ; oxide |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 4290 |
| 语种 | 英语 |
| WOS记录号 | WOS:000330779900048 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119790]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Fuel Cells, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Li,Yu, Hongmei,Li, Yongkun,et al. Ethylene glycol adjusted nanorod hematite film for active photoelectrochemical water splitting[J]. physical chemistry chemical physics,2014,16(9):4284-4290. |
| APA | Fu, Li.,Yu, Hongmei.,Li, Yongkun.,Zhang, Changkun.,Wang, Xunying.,...&Yi, Baolian.(2014).Ethylene glycol adjusted nanorod hematite film for active photoelectrochemical water splitting.physical chemistry chemical physics,16(9),4284-4290. |
| MLA | Fu, Li,et al."Ethylene glycol adjusted nanorod hematite film for active photoelectrochemical water splitting".physical chemistry chemical physics 16.9(2014):4284-4290. |
入库方式： OAI收割
来源：大连化学物理研究所
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