中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Amide-functionalized carbon supports for cobalt oxide toward oxygen reduction reaction in Zn-air battery

文献类型:期刊论文

作者Liu, Jing1,2; Jiang, Luhua1; Tang, Qiwen1; Wang, Erdong1; Qi, Luting1; Wang, Suli1; Sun, Gongquan1
刊名applied catalysis b-environmental
出版日期2014-04-27
卷号148页码:212-220
关键词Oxygen reduction reaction Carbon surface Functional group Cobalt oxide Zn-air battery
产权排序待补充
通讯作者孙公权
合作状况
英文摘要n-doped carbon materials are extensively reported active toward the oxygen reduction reaction (orr). different from n-doped carbon, in this study, we report a kind of non-doped nitrogen, i.e., amide-groups, over carbon surface promoting the orr activity of a coox/c-n composite. the amide-groups are successfully grafted over carbon surface (c-n) via a simple solvothermal route demonstrated by fourier transform infrared spectra (ftir) and x-ray photoelectron spectroscope (xps). after loaded cobalt oxide nanoparticles of around 2 nm in average, the amide-group grafting carbon shows enhanced activity toward the orr compared to its counterparts with carboxyl-group or the pristine carbon. for the first time, as known, the coox/c composite is used as the cathodic catalyst for the zn-air battery, and the peak power density reaches up to 100-123 mw cm(-2), demonstrating the promising practical application in zn-air battery. the enhanced orr activity of the coox/c-n composite is probably related with the higher content of coo in the composite surface induced by the amide group over carbon surface. crown copyright (c) 2013 published by elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
学科主题物理化学
类目[WOS]chemistry, physical ; engineering, environmental ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]effective core potentials ; nitrogen-doped graphene ; molecular calculations ; alkaline media ; fuel-cells ; electrocatalysts ; catalysts ; spectroscopy ; pretreatment ; composites
收录类别SCI
资助信息1,1
原文出处220
语种英语
WOS记录号WOS:000332431500023
公开日期2014-09-11
源URL[http://159.226.238.44/handle/321008/119797]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China
推荐引用方式
GB/T 7714
Liu, Jing,Jiang, Luhua,Tang, Qiwen,et al. Amide-functionalized carbon supports for cobalt oxide toward oxygen reduction reaction in Zn-air battery[J]. applied catalysis b-environmental,2014,148:212-220.
APA Liu, Jing.,Jiang, Luhua.,Tang, Qiwen.,Wang, Erdong.,Qi, Luting.,...&Sun, Gongquan.(2014).Amide-functionalized carbon supports for cobalt oxide toward oxygen reduction reaction in Zn-air battery.applied catalysis b-environmental,148,212-220.
MLA Liu, Jing,et al."Amide-functionalized carbon supports for cobalt oxide toward oxygen reduction reaction in Zn-air battery".applied catalysis b-environmental 148(2014):212-220.

入库方式: OAI收割

来源:大连化学物理研究所

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