The Effect of Additive on the Performance and Phase Separation of Benzo[1,2-b:3,4-b]dithiophene-Based Polymer Heterojunction Photovoltaic Devices
文献类型：期刊论文
| 作者 | Ni, Nan1,2; Qu, Bo3; Tian, Di2; Cong, Zhiyuan2; Wang, Weiping2; Gao, Chao2,4; Xiao, Lixin3; Chen, Zhijian3; Gong, Qihuang3; Wei, Wei1 |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 2013-05-14 |
| 卷号 | 214期号:9页码:985-993 |
| 关键词 | additives phase separation 1 8-diiodooctane polymer solar cells |
| ISSN号 | 1022-1352 |
| 通讯作者 | 国外 |
| 英文摘要 | an alternating copolymer (pbdtc10dbt) of benzo[1,2-b:3,4-b]dithiophene (bdt) as donor and 4,7-di(3-decylthiophen-2-yl)-2,1,3-benzothiadiazole (c10dbt) as acceptor is designed and synthesized. in order to investigate the effect of the 1,8-diiodooctane (dio) additive on the morphology and photovoltaic performance, polymer solar cells (pscs) based on pbdtc10dbt:[6,6]-phenyl-c61-butyric acid methyl ester (pc61bm) are fabricated. the morphology of blend films and the interpenetrating network between the donor and the acceptor is examined using atomic force microscopy and scanning electron microscopy. this work shows that the pbdtc10dbt:pc61bm blend films with added dio (3%, v/v) have improved absorption and controlled phase separation. morphology with a domain size of 2030 nm that forms in the dio system is proposed to facilitate charge transport and minimize charge carrier recombination, which are the main reasons why the power conversion efficiency of the pscs is improved from 1.93% (without dio) to 2.23% (with dio). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | low-bandgap polymer ; solar-cells ; efficiency ; morphology ; network |
| 收录类别 | SCI ; EI |
| 语种 | 英语 |
| WOS记录号 | WOS:000318353900004 |
| 公开日期 | 2014-09-17 |
| 源URL | [http://ir.opt.ac.cn/handle/181661/22069]  |
| 专题 | 西安光学精密机械研究所_先进光电与生物材料研发中心 |
| 作者单位 | 1.Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210003, Peoples R China 2.Xian Modern Chem Res Inst, Xian 710065, Shanxi, Peoples R China 3.Peking Univ, State Key Lab Artificial Microstruct & Mesoscop P, Dept Phys, Beijing 100871, Peoples R China 4.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ni, Nan,Qu, Bo,Tian, Di,et al. The Effect of Additive on the Performance and Phase Separation of Benzo[1,2-b:3,4-b]dithiophene-Based Polymer Heterojunction Photovoltaic Devices[J]. macromolecular chemistry and physics,2013,214(9):985-993. |
| APA | Ni, Nan.,Qu, Bo.,Tian, Di.,Cong, Zhiyuan.,Wang, Weiping.,...&Wei, Wei.(2013).The Effect of Additive on the Performance and Phase Separation of Benzo[1,2-b:3,4-b]dithiophene-Based Polymer Heterojunction Photovoltaic Devices.macromolecular chemistry and physics,214(9),985-993. |
| MLA | Ni, Nan,et al."The Effect of Additive on the Performance and Phase Separation of Benzo[1,2-b:3,4-b]dithiophene-Based Polymer Heterojunction Photovoltaic Devices".macromolecular chemistry and physics 214.9(2013):985-993. |
入库方式： OAI收割
来源：西安光学精密机械研究所
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