中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Extraction of alumina from coal fly ash by mixed-alkaline hydrothermal method

文献类型:期刊论文

作者Li, Huiquan1; Hui, Junbo1,2; Wang, Chenye1; Bao, Weijun1; Sun, Zhenhua1
刊名HYDROMETALLURGY
出版日期2014-08-01
卷号147期号:8m页码:183-187
关键词Alumina Coal fly ash Alkaline hydrothermal Extraction
ISSN号0304-386X
其他题名Hydrometallurgy
中文摘要Alumina was leached from coal fly ash using a mixed alkali (NaOH + Ca(OH)(2)) through the hydrothermal method. The effects of leaching conditions on the alumina were studied, and the results showed that the alumina extraction ratio increased with increased reaction temperature, calcium-silicon ratio, and liquid-solid ratio. By optimising the leaching conditions, the alumina extraction ratio could reach 91.3%. The obtained leaching residues were analysed by X-ray diffraction (XRD) and scanning electron microscope (SEM) + energy dispersive spectrometer (EDS), and the reaction mechanism was also discussed. Results showed that amorphous silica and mullite were first dissolved and transformed into hydro-sodalite at relatively low temperatures. Hydro-sodalite reacted with calcium hydroxide to form sodium calcium silicate (NaCaHSiO4), which was the major component of the leaching residue. Zeolite was the equilibrium product, which accounted for most of the alumina leaching loss. The addition of Ca(OH)(2) effectively inhibited the silicon leaching into the solution. (C) 2014 Elsevier B.V. All rights reserved.
英文摘要Alumina was leached from coal fly ash using a mixed alkali (NaOH + Ca(OH)(2)) through the hydrothermal method. The effects of leaching conditions on the alumina were studied, and the results showed that the alumina extraction ratio increased with increased reaction temperature, calcium-silicon ratio, and liquid-solid ratio. By optimising the leaching conditions, the alumina extraction ratio could reach 91.3%. The obtained leaching residues were analysed by X-ray diffraction (XRD) and scanning electron microscope (SEM) + energy dispersive spectrometer (EDS), and the reaction mechanism was also discussed. Results showed that amorphous silica and mullite were first dissolved and transformed into hydro-sodalite at relatively low temperatures. Hydro-sodalite reacted with calcium hydroxide to form sodium calcium silicate (NaCaHSiO4), which was the major component of the leaching residue. Zeolite was the equilibrium product, which accounted for most of the alumina leaching loss. The addition of Ca(OH)(2) effectively inhibited the silicon leaching into the solution. (C) 2014 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Technology
类目[WOS]Metallurgy & Metallurgical Engineering
研究领域[WOS]Metallurgy & Metallurgical Engineering
收录类别SCI
原文出处://WOS:000340333100026
语种英语
WOS记录号WOS:000340333100026
公开日期2014-09-30
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/11436]  
专题过程工程研究所_研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li, Huiquan,Hui, Junbo,Wang, Chenye,et al. Extraction of alumina from coal fly ash by mixed-alkaline hydrothermal method[J]. HYDROMETALLURGY,2014,147(8m):183-187.
APA Li, Huiquan,Hui, Junbo,Wang, Chenye,Bao, Weijun,&Sun, Zhenhua.(2014).Extraction of alumina from coal fly ash by mixed-alkaline hydrothermal method.HYDROMETALLURGY,147(8m),183-187.
MLA Li, Huiquan,et al."Extraction of alumina from coal fly ash by mixed-alkaline hydrothermal method".HYDROMETALLURGY 147.8m(2014):183-187.

入库方式: OAI收割

来源:过程工程研究所

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