Ni0.33Mn0.33Co0.33Fe2O4 nanoparticles anchored on oxidized carbon nanotubes as advanced anode materials in Li-ion batteries
文献类型：期刊论文
| 作者 | Zhang, Zailei1; Kan, Guangwei1; Ren, Wenfeng1; Tan, Qiangqiang1; Zhong, Ziyi2; Su, Fabing1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:64页码:33769-33775 |
| 关键词 | LITHIUM STORAGE PROPERTIES HIGH-PERFORMANCE ANODE NEGATIVE-ELECTRODE MATERIALS ENERGY-STORAGE HOLLOW MICROSPHERES FACILE SYNTHESIS FULLERENE PIPES BINDER-FREE METAL CAPACITY |
| ISSN号 | 2046-2069 |
| 其他题名 | RSC Adv. |
| 中文摘要 | We report a solvothermal synthesis of Ni0.33Mn0.33Co0.33Fe2O4 (NMCFO) nanoparticles anchored on the surface of oxidized carbon nanotubes (OCNT) to form NMCFO/OCNT nanocomposites as advanced anode materials in Li-ion batteries. Ni(CH3COO)(2), Mn(CH3COO)(2), Co(CH3COO)(2), and FeCl3 were employed as the metal precursors and CH3COONa, HOCH2CH2OH and H2O as the mixed solvent in the synthesis. The obtained samples were characterized by X-ray diffraction, thermogravimetric analysis, inductively coupled plasma optical emission spectrometry, X-ray photoelectron spectroscopy, transmission electron microscopy, and scanning electron microscopy. It is found that the OCNT provided functional groups on the outer walls to nucleate and anchor NMCFO nanoparticles (5-20 nm), while retaining the inner walls intact with high conductivity. Compared with the bare NMCFO nanoparticles, NMCFO/OCNT composites showed a significantly improved electrochemical performance because OCNT can substantially inhibit the aggregation of NMCFO nanoparticles and buffer the volume change, and moreover, the inner walls of OCNT provide excellent electronic conduction pathways. This work opens an effective way for the fabrication of ferrite-based metal oxide/OCNT hybrids as promising anode materials for Li-ion batteries. |
| 英文摘要 | We report a solvothermal synthesis of Ni0.33Mn0.33Co0.33Fe2O4 (NMCFO) nanoparticles anchored on the surface of oxidized carbon nanotubes (OCNT) to form NMCFO/OCNT nanocomposites as advanced anode materials in Li-ion batteries. Ni(CH3COO)(2), Mn(CH3COO)(2), Co(CH3COO)(2), and FeCl3 were employed as the metal precursors and CH3COONa, HOCH2CH2OH and H2O as the mixed solvent in the synthesis. The obtained samples were characterized by X-ray diffraction, thermogravimetric analysis, inductively coupled plasma optical emission spectrometry, X-ray photoelectron spectroscopy, transmission electron microscopy, and scanning electron microscopy. It is found that the OCNT provided functional groups on the outer walls to nucleate and anchor NMCFO nanoparticles (5-20 nm), while retaining the inner walls intact with high conductivity. Compared with the bare NMCFO nanoparticles, NMCFO/OCNT composites showed a significantly improved electrochemical performance because OCNT can substantially inhibit the aggregation of NMCFO nanoparticles and buffer the volume change, and moreover, the inner walls of OCNT provide excellent electronic conduction pathways. This work opens an effective way for the fabrication of ferrite-based metal oxide/OCNT hybrids as promising anode materials for Li-ion batteries. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | LITHIUM STORAGE PROPERTIES ; HIGH-PERFORMANCE ANODE ; NEGATIVE-ELECTRODE MATERIALS ; ENERGY-STORAGE ; HOLLOW MICROSPHERES ; FACILE SYNTHESIS ; FULLERENE PIPES ; BINDER-FREE ; METAL ; CAPACITY |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000341287300018 |
| 公开日期 | 2014-09-30 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/11622]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.ASTAR, Inst Chem Engn & Sci, Singapore 627833, Singapore |
| 推荐引用方式 GB/T 7714 | Zhang, Zailei,Kan, Guangwei,Ren, Wenfeng,et al. Ni0.33Mn0.33Co0.33Fe2O4 nanoparticles anchored on oxidized carbon nanotubes as advanced anode materials in Li-ion batteries[J]. RSC ADVANCES,2014,4(64):33769-33775. |
| APA | Zhang, Zailei,Kan, Guangwei,Ren, Wenfeng,Tan, Qiangqiang,Zhong, Ziyi,&Su, Fabing.(2014).Ni0.33Mn0.33Co0.33Fe2O4 nanoparticles anchored on oxidized carbon nanotubes as advanced anode materials in Li-ion batteries.RSC ADVANCES,4(64),33769-33775. |
| MLA | Zhang, Zailei,et al."Ni0.33Mn0.33Co0.33Fe2O4 nanoparticles anchored on oxidized carbon nanotubes as advanced anode materials in Li-ion batteries".RSC ADVANCES 4.64(2014):33769-33775. |
入库方式： OAI收割
来源：过程工程研究所
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