Total Synthesis of (-)-Orthodiffenes A and C
文献类型:期刊论文
作者 | Liu, Jun ; Liu, Yi ; Zhang, Xing ; Zhang, Chaoli ; Gao, Yangguang ; Wang, LinLin ; Du, Yuguo |
刊名 | JOURNAL OF ORGANIC CHEMISTRY
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出版日期 | 2012 |
卷号 | 77期号:21页码:9718-9723 |
ISSN号 | 0022-3263 |
中文摘要 | The efficient and concise synthesis of (-)-orthodiffenes A and C has been accomplished for the first time in eight steps from readily available chiral synthons, D-mannose and D-ethyl lactate. Our work confirmed the complete structure of orthodiffenes A and C, including their absolute stereochemistry. The key steps of our total synthesis involved cis-fused tetrahydrofuran cyclization, one-pot deprotection-lactonization, and intramolecular benzoyl migration according to a biosynthetic hypothesis of orthodiffenes. |
WOS记录号 | WOS:000311190200031 |
公开日期 | 2014-11-04 |
源URL | [http://ir.rcees.ac.cn/handle/311016/7723] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Liu, Jun,Liu, Yi,Zhang, Xing,et al. Total Synthesis of (-)-Orthodiffenes A and C[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(21):9718-9723. |
APA | Liu, Jun.,Liu, Yi.,Zhang, Xing.,Zhang, Chaoli.,Gao, Yangguang.,...&Du, Yuguo.(2012).Total Synthesis of (-)-Orthodiffenes A and C.JOURNAL OF ORGANIC CHEMISTRY,77(21),9718-9723. |
MLA | Liu, Jun,et al."Total Synthesis of (-)-Orthodiffenes A and C".JOURNAL OF ORGANIC CHEMISTRY 77.21(2012):9718-9723. |
入库方式: OAI收割
来源:生态环境研究中心
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