Adsorption of fluoride onto different types of aluminas
文献类型：期刊论文
| 作者 | Gong, Wen-Xin ; Qu, Jiu-Hui ; Liu, Rui-Ping ; Lan, Hua-Chun |
| 刊名 | Engineering
 |
| 出版日期 | 2012 |
| 卷号 | 189期号:1页码:126-133 |
| 关键词 | Fluoride Adsorption Alumina Ion exchange Acidity |
| ISSN号 | 1385-8947 |
| 中文摘要 | In this study, five aluminas were synthesized at different pH and calcination temperatures, and the surface properties and defluoridation performance of aluminas were investigated. Characterization of XRD showed that five aluminas were poorly crystallized with different phases and their anion exchange capacity and the point of zero charge varied with the species of aluminas. The batch experiments (thermodynamics, kinetics and the effect of pH) were conducted to evaluate the fluoride adsorption behavior of different aluminas. For all aluminas, both Langmiur and Freundlich models fitted the adsorption isotherms well and the calculation of thermodynamics showed that adsorption was spontaneous and endothermic; the kinetics was well described by the pseudo-second-order model and the weak acidic pH favored the fluoride adsorption. Acidity/basicity of alumina exhibited significant effect on the behaviors of adsorption and the process of ion exchange in fluoride removal. Acidic alumina exhibited higher ion exchange capacity, more positively charged surface, and better defluoridation performance (higher adsorption capacity and quicker removal of fluoride) than basic alumina. Acidic alumina also showed higher efficiency when treating natural ground water without pH adjustment. The difference in the adsorption properties was ascribed to the different exchange sites and the different behaviors of anion exchange. In the case of acidic alumina, more Cl- was exchanged with fluoride and the adsorption/release of OH- was dependent on the initial fluoride concentration. For basic alumina most of exchange sites were provided by OH- and fluoride was removed through the exchange between fluoride and OH-. (C) 2012 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000303639300017 |
| 公开日期 | 2014-11-28 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/8111]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Gong, Wen-Xin,Qu, Jiu-Hui,Liu, Rui-Ping,et al. Adsorption of fluoride onto different types of aluminas[J]. Engineering,2012,189(1):126-133. |
| APA | Gong, Wen-Xin,Qu, Jiu-Hui,Liu, Rui-Ping,&Lan, Hua-Chun.(2012).Adsorption of fluoride onto different types of aluminas.Engineering,189(1),126-133. |
| MLA | Gong, Wen-Xin,et al."Adsorption of fluoride onto different types of aluminas".Engineering 189.1(2012):126-133. |
入库方式： OAI收割
来源：生态环境研究中心
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