Deep catalytic oxidation of benzene, toluene, ethyl acetate over Pd/SBA-15 catalyst: reaction behaviors and kinetics
文献类型：期刊论文
| 作者 | He, Chi ; Yue, Lin ; Zhang, Xinyan ; Li, Peng ; Dou, Baojuan ; Ma, Chunyan ; Hao, Zhengping |
| 刊名 | Engineering
 |
| 出版日期 | 2012 |
| 卷号 | 7期号:5页码:705-715 |
| 关键词 | Pd SBA-15 catalytic oxidation VOCs mutual effects kinetics |
| ISSN号 | 1932-2135 |
| 中文摘要 | This work aimed at investigating the reaction behaviors and kinetics of catalytic oxidation of benzene, toluene, and ethyl acetate over Pd/SBA-15 catalyst. Results for single components show that toluene (T50 = 185215 degrees C) is more easily oxidized than ethyl acetate (T50 = 220255 degrees C) and benzene (T50 = 215290 degrees C). The conversion of toluene and benzene decreases continuously as their inlet concentrations are increased. The conversion of ethyl acetate increases slightly when its feed concentration increases in a small range, while this trend is not kept when the concentration is further raised. Results for multicomponents reveal that the presence of benzene or toluene inhibits the conversion of ethyl acetate, and the aromatic hydrocarbons inhibit each other. Ethyl acetate has an inhibitory effect on benzene, while it is interested to note that the promotion behaviors are observed for toluene. Kinetic results of all studied volatile organic compounds obtained in the absence of diffusion limitations are fit to the Mars-van Krevelen expressions. (c) 2011 Curtin University of Technology and John Wiley & Sons, Ltd. |
| WOS记录号 | WOS:000309459200010 |
| 公开日期 | 2014-11-28 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/8094]  |
| 专题 | 生态环境研究中心_环境纳米材料实验室 |
| 推荐引用方式 GB/T 7714 | He, Chi,Yue, Lin,Zhang, Xinyan,et al. Deep catalytic oxidation of benzene, toluene, ethyl acetate over Pd/SBA-15 catalyst: reaction behaviors and kinetics[J]. Engineering,2012,7(5):705-715. |
| APA | He, Chi.,Yue, Lin.,Zhang, Xinyan.,Li, Peng.,Dou, Baojuan.,...&Hao, Zhengping.(2012).Deep catalytic oxidation of benzene, toluene, ethyl acetate over Pd/SBA-15 catalyst: reaction behaviors and kinetics.Engineering,7(5),705-715. |
| MLA | He, Chi,et al."Deep catalytic oxidation of benzene, toluene, ethyl acetate over Pd/SBA-15 catalyst: reaction behaviors and kinetics".Engineering 7.5(2012):705-715. |
入库方式： OAI收割
来源：生态环境研究中心
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