Selective Hydrogenation of Cinnamaldehyde over Pt and Pd Supported on Multiwalled Carbon Nanotubes in a CO2-Expanded Alcoholic Medium
文献类型：期刊论文
| 作者 | Zhao, Bao-Hui ; Chen, Jian-Gang ; Liu, Xuan ; Liu, Zhong-Wen ; Hao, Zhengping ; Xiao, Jianliang ; Liu, Zhao-Tie |
| 刊名 | Engineering
 |
| 出版日期 | 2012 |
| 卷号 | 51期号:34页码:11112-11121 |
| ISSN号 | 0888-5885 |
| 中文摘要 | Pt/MWCNT and Pd/MWCNT nanocatalysts were prepared via a liquid reduction method. The selective hydrogenation of cinnamaldehyde (CAL) was investigated over 5.0 wt.% Pt/MWCNT and 5.0 wt.% Pd/MWCNT catalysts in a CO2-expanded alcoholic medium at different reaction conditions. The hydrogenation selectivities over these two catalyst types were shown to be entirely different. It was found that the Pt/MWCNT catalysts are highly selective for C=O bonds, giving the unsaturated alcohol a selectivity for cinnamyl alcohol (COL) of 97.3% and a conversion rate for cinnamaldehyde of 99.3%. Conversely, the Pd/MWCNT catalyst is highly selective for C=C bonds, producing a saturated aldehyde with a selectivity for hydrocinnamaldehyde (HCAL) of 91.3% and a conversion rate for cinnamaldehyde of 98.6%. The small diameter of the Pt or Pd granules over the multiwalled carbon nanotubes (MWCNTs) leads to a high catalyst activity, and an increase of CO2 pressure results in a better hydrogenation performance for C=O bonds than that for C=C bonds. |
| WOS记录号 | WOS:000308043500016 |
| 公开日期 | 2014-11-28 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/8107]  |
| 专题 | 生态环境研究中心_环境纳米材料实验室 |
| 推荐引用方式 GB/T 7714 | Zhao, Bao-Hui,Chen, Jian-Gang,Liu, Xuan,et al. Selective Hydrogenation of Cinnamaldehyde over Pt and Pd Supported on Multiwalled Carbon Nanotubes in a CO2-Expanded Alcoholic Medium[J]. Engineering,2012,51(34):11112-11121. |
| APA | Zhao, Bao-Hui.,Chen, Jian-Gang.,Liu, Xuan.,Liu, Zhong-Wen.,Hao, Zhengping.,...&Liu, Zhao-Tie.(2012).Selective Hydrogenation of Cinnamaldehyde over Pt and Pd Supported on Multiwalled Carbon Nanotubes in a CO2-Expanded Alcoholic Medium.Engineering,51(34),11112-11121. |
| MLA | Zhao, Bao-Hui,et al."Selective Hydrogenation of Cinnamaldehyde over Pt and Pd Supported on Multiwalled Carbon Nanotubes in a CO2-Expanded Alcoholic Medium".Engineering 51.34(2012):11112-11121. |
入库方式： OAI收割
来源：生态环境研究中心
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