Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5
文献类型:期刊论文
作者 | Guo, Xinfeng; Wu, Hongping; Pan, Shilie![]() ![]() |
刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
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出版日期 | 2014 |
卷号 | 640期号:8-9页码:1805-1809 |
关键词 | Borates Congruent melting compound Magnesium MgSrB2O5 Diborate |
ISSN号 | 0044-2313 |
英文摘要 | A congruent melting compound MgSrB2O5 was synthesized by high temperature solution method from the MgO-SrO-B2O3 system, and the structure was determined by single-crystal X-ray diffraction methods. The compound crystallizes in the monoclinic system, with space group P2(1)/c. The crystal structure is composed of isolated B2O5 units and MgO6 octahedra that are connected to form two-dimensional [Mg2B4O10] layers stacking along the c axis. The layers are bridged by the Sr2+ cations to form a three-dimensional framework. The IR spectrum and the thermal properties of MgSrB2O5 were also reported. Additionally, detailed structure comparisons between MgSrB2O5 and other borates, such as Mg2B2O5, Sr2B2O5 and SrCdB2O5 are carried out and the first-principle theoretical studies are performed to aid the understanding of electronic structures and linear optical properties. |
收录类别 | SCI |
WOS记录号 | WOS:000339561500043 |
公开日期 | 2014-11-11 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/3764] ![]() |
专题 | 新疆理化技术研究所_支撑部门 新疆理化技术研究所_材料物理与化学研究室 |
作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Xinfeng,Wu, Hongping,Pan, Shilie,et al. Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2014,640(8-9):1805-1809. |
APA | Guo, Xinfeng.,Wu, Hongping.,Pan, Shilie.,Yang, Zhihua.,Yu, Hongwei.,...&Zhang, Fangyuan.(2014).Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,640(8-9),1805-1809. |
MLA | Guo, Xinfeng,et al."Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 640.8-9(2014):1805-1809. |
入库方式: OAI收割
来源:新疆理化技术研究所
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