The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)
文献类型：期刊论文
| 作者 | Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie ; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping; Yang, Zhihua; Wang, Xian
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| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2014 |
| 期号 | 22页码:3467-3473 |
| 关键词 | Synthesis design Chain structures Borates Phosphates Lead |
| ISSN号 | 1434-1948 |
| 通讯作者 | Han, J |
| 英文摘要 | Compounds containing both B-O and P-O groups are of wide interest and have been classified into borophosphates and borate-phosphates by R. Kniep et al. In addition to the B/P ratio, analysis results show that regulating the [M/(B+P)] ratio is also an effective strategy to synthesize new borate-phosphates. The first lithium lead borate-phosphate, LiPb4(BO3)(PO4)(2), was synthesized by regulating this ratio. This compound crystallizes in the orthorhombic space group Pbca (No. 61). It possesses a 3D structure with a corrugated 2D layer of [B2Pb8O18] that is further connected by a [LiP2O8] chain; both BO3 and PO4 were isolated. First-principle theoretical studies were performed to aid the understanding of the electronic structures and the linear optical properties. In addition, thermal analysis, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy were performed on the reported material. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000340416000004 |
| 公开日期 | 2014-11-11 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/3755]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Shengshi,Yu, Hongwei,Han, Jian,et al. The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2014(22):3467-3473. |
| APA | Huang, Shengshi.,Yu, Hongwei.,Han, Jian.,Pan, Shilie.,Jing, Qun.,...&Wang, Xian.(2014).The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(22),3467-3473. |
| MLA | Huang, Shengshi,et al."The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .22(2014):3467-3473. |
入库方式： OAI收割
来源：新疆理化技术研究所
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