Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals
文献类型：期刊论文
| 作者 | Bai, Chunyan; Lei, Chen; Pan, Shilie ; Wang, Ying; Yang, Zhihua; Han, Shujuan; Yu, Hongwei; Yang, Yun; Zhang, Fangyuan
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| 刊名 | Solid State Sciences
 |
| 出版日期 | 2014 |
| 卷号 | 33期号:7页码:32-37 |
| 关键词 | Rb3Na(MoO4)(2) Rb3Na(WO4)(2) Crystal structure X-ray diffraction |
| ISSN号 | 12932558 |
| 通讯作者 | Pan, SL |
| 英文摘要 | Two new compounds, Rb3Na(MoO4)2 and Rb3Na(WO4)2, have been synthesized by conventional solid-state reaction. Single-crystal X-ray diffraction analysis revealed that they crystallize in the same space group P3¯m1 (No. 164) with the trigonal unit cell sizes of a = 6.138(2) A˚, c = 7.844(3) A˚ for the Mo compound and a = 6.161(4) A˚, c = 7.847(6) A˚ for the W compound. Both structures contain an infinite three-dimensional (3D) matrix that is built from isolated MO4 (M = Mo, W) tetrahedra, Rb(1)O 12, Rb(2)O10 polyhedra and NaO6 octahedra. In addition, the infrared spectroscopy spectrum (IR) and bond valence sums (BVS) calculations are used to verify the validity of the structures. The differential scanning calorimetry (DSC) and powder X-ray diffraction (XRD) results prove that both of them are congruently melting compounds. And the first-principle theoretical studies are also carried out to aid the understanding of their electronic structures. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000338623500006 |
| 公开日期 | 2014-11-11 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/3765]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bai, Chunyan,Lei, Chen,Pan, Shilie,et al. Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals[J]. Solid State Sciences,2014,33(7):32-37. |
| APA | Bai, Chunyan.,Lei, Chen.,Pan, Shilie.,Wang, Ying.,Yang, Zhihua.,...&Zhang, Fangyuan.(2014).Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals.Solid State Sciences,33(7),32-37. |
| MLA | Bai, Chunyan,et al."Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals".Solid State Sciences 33.7(2014):32-37. |
入库方式： OAI收割
来源：新疆理化技术研究所
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