A Nitrate Nonlinear Optical Crystal Pb-16(OH)(16)(NO3)(16) with a Large Second-Harmonic Generation Response
文献类型：期刊论文
| 作者 | Chang, Lixian; Wang, Li; Su, Xin; Pan, Shilie ; Hailili, Reshalaiti; Yu, Hongwei; Yang, Zhihua
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| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 53期号:7页码:3320-3325 |
| ISSN号 | 0020-1669 |
| 英文摘要 | A noncentrosymmetric nitrate, Pb-16(OH)(16)(NO3)(16), has been obtained using a hydrothermal method. It is constructed of [Pb-4(OH)(4)](4+) cubanes and nitrate form the overall three-dimensional structure via weak Pb-O bonds. Powder second-harmonic generation (SHG) using the Kurtz-Perry technique shows that Pb-16(OH)(16)(NO3)(16) is type I phase-matchable, and the measured SHG coefficient was 3.5 times that of KH2PO4. The direction and magnitude of the dipole moments in PbOn polyhedra and [NO3](-) triangles of Pb-16(OH)(16)(NO3)(16) have been quantified using the bond-valence approach, which shows that the large SHG response originates from the cooperation of PbOn polyhedra and [NO3](-) triangles. The band structure and density of states as well as electron density difference are calculated on the basis of density functional theory. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000334092500014 |
| 公开日期 | 2014-11-11 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/3790]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chang, Lixian,Wang, Li,Su, Xin,et al. A Nitrate Nonlinear Optical Crystal Pb-16(OH)(16)(NO3)(16) with a Large Second-Harmonic Generation Response[J]. INORGANIC CHEMISTRY,2014,53(7):3320-3325. |
| APA | Chang, Lixian.,Wang, Li.,Su, Xin.,Pan, Shilie.,Hailili, Reshalaiti.,...&Yang, Zhihua.(2014).A Nitrate Nonlinear Optical Crystal Pb-16(OH)(16)(NO3)(16) with a Large Second-Harmonic Generation Response.INORGANIC CHEMISTRY,53(7),3320-3325. |
| MLA | Chang, Lixian,et al."A Nitrate Nonlinear Optical Crystal Pb-16(OH)(16)(NO3)(16) with a Large Second-Harmonic Generation Response".INORGANIC CHEMISTRY 53.7(2014):3320-3325. |
入库方式： OAI收割
来源：新疆理化技术研究所
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