Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O
文献类型：期刊论文
| 作者 | Chen, Zhaohui; Pan, Shilie ; Jing, Qun; Yang, Yun; Dong, Xiaoyu; Bian, Qiang; Han, Jian; Dong, Lingyun; Yang, Zhihua
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| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
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| 出版日期 | 2014 |
| 卷号 | 640期号:1页码:140-146 |
| 关键词 | Crystal structure Crystal growth Organic-inorganic hybrid Nonlinear optical materials |
| ISSN号 | 0044-2313 |
| 英文摘要 | The organic-inorganic hybrid nonlinear optical (NLO) material NH4B(d-(+)-C4H4O5)(2)H2O (NBC) was synthesized in a borate-carboxylic acid system. Its structure was determined by single crystal X-ray diffraction. It crystallizes in the orthorhombic system, space group Pna2(1) (No. 33), with cell parameters a = 11.484(6) angstrom, b = 5.354(3) angstrom, c = 21.079(12) angstrom, V = 1296.0(12), Z = 4. It exhibits a three-dimensional pseudo tunnel structure consisting of fundamental building block [B(d-(+)-C4H4O5)(2)](-) anions. The small cavities are occupied by the H2O molecules and NH4+ cations, which stabilize the whole structure by O-HO and N-HO hydrogen bonds. The powder X-ray diffraction (PXRD) of the crystal was also recorded. Elemental analyses, FT-IR and FT-Raman spectra analyses, thermal analysis, and diffuse-reflectance spectra for the compound are also presented, as are band structures and density of states calculation. Nonlinear optical measurements indicate that the material has second harmonic generation (SHG) properties and is phase-matchable. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000330595800024 |
| 公开日期 | 2014-11-11 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/3839]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Univ, Phys & Chem Testing Ctr, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Zhaohui,Pan, Shilie,Jing, Qun,et al. Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2014,640(1):140-146. |
| APA | Chen, Zhaohui.,Pan, Shilie.,Jing, Qun.,Yang, Yun.,Dong, Xiaoyu.,...&Yang, Zhihua.(2014).Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,640(1),140-146. |
| MLA | Chen, Zhaohui,et al."Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 640.1(2014):140-146. |
入库方式： OAI收割
来源：新疆理化技术研究所
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