Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains
文献类型：期刊论文
| 作者 | Wang, Zheng; Zhang, Min ; Pan, Shilie; Wang, Ying; Zhang, Hui; Chen, Zhaohui; Zhang, M.
|
| 刊名 | Dalton Transactions
 |
| 出版日期 | 2014 |
| 卷号 | 43期号:7页码:2828-2834 |
| ISSN号 | 14779226 |
| 通讯作者 | Zhang, M. |
| 英文摘要 | The first alkali metal and magnesium mixed borate fluoride, Li 0.8Mg2.1B2O5F, was prepared by the high-temperature solution method. It crystallizes in the monoclinic space group P21/n (no. 14) with lattice constants a = 3.0881(4) A˚, b = 13.6020(2) A˚, c = 9.6563(1) A˚, β = 91.744(9)°, Z = 4. In the structure, a special magnesium-oxygen-fluorine octahedral chain is found in borates for the first time. The octahedral chains are linked into a three-dimensional framework containing tunnels with 1 ∞[LiO4]7- chains and isolated B 2O5 groups filling in. The differences of octahedral chains in Li0.8Mg2.1B2O5F and magnesium inosilicate minerals are discussed. The TG-DSC curves, IR spectrum and UV-Vis-NIR diffuse reflectance spectrum were measured. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000330118000018 |
| 公开日期 | 2014-11-11 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/3840]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 |
| 通讯作者 | Zhang, M. |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat, Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zheng,Zhang, Min,Pan, Shilie,et al. Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains[J]. Dalton Transactions,2014,43(7):2828-2834. |
| APA | Wang, Zheng.,Zhang, Min.,Pan, Shilie.,Wang, Ying.,Zhang, Hui.,...&Zhang, M..(2014).Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains.Dalton Transactions,43(7),2828-2834. |
| MLA | Wang, Zheng,et al."Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains".Dalton Transactions 43.7(2014):2828-2834. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。