Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain
文献类型：期刊论文
| 作者 | YuHongwei; WuHongping; PanShilie ; ZhangBingbing; DongLingyun; HanShujuan; YangZhihua
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| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 38期号:1页码:285-291 |
| ISSN号 | 1144-0546 |
| 英文摘要 | A new lead zinc borate, Pb4Zn2B10O21, has been synthesized and the crystal structure was determined by single crystal X-ray diffraction. It crystallizes in the orthorhombic group Pbcn with a = 14.6062(15) angstrom, b = 17.4899(16) angstrom, c = 13.2962(15) angstrom, Z = 8. Interestingly, in the crystal structure, a new B-O building unit [B10O24] group is observed and the four different coordinated Pb atoms are connected with each other by sharing a corner, edge or face to form an interesting regular [Pb4O12](infinity) chain. The DSC analysis proves that Pb4Zn2B10O21 melts congruently. First-principles electronic structure calculation shows that the calculated band gap of Pb4Zn2B10O21 is 3.53 eV, which is in good agreement with the experimental value measured from the UV-vis-NIR absorption spectrum, and the observed absorption peak is assigned as a charge transfer from O 2p states to Pb 6p states. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000329886900037 |
| 公开日期 | 2014-11-11 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/3842]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 |
| 作者单位 | Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | YuHongwei,WuHongping,PanShilie,et al. Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain[J]. NEW JOURNAL OF CHEMISTRY,2014,38(1):285-291. |
| APA | YuHongwei.,WuHongping.,PanShilie.,ZhangBingbing.,DongLingyun.,...&YangZhihua.(2014).Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain.NEW JOURNAL OF CHEMISTRY,38(1),285-291. |
| MLA | YuHongwei,et al."Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain".NEW JOURNAL OF CHEMISTRY 38.1(2014):285-291. |
入库方式： OAI收割
来源：新疆理化技术研究所
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