Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes
文献类型：期刊论文
| 作者 | Hu HY(胡红岩)1 ; Jiao ZB(焦正波)1; Ye JH(叶金花)2; Lu GX(吕功煊)1; Bi YP(毕迎普)1; Bi YP(毕迎普)
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| 刊名 | Nano Energy
 |
| 出版日期 | 2014 |
| 卷号 | 8页码:103-109 |
| 关键词 | Cannizzaro reaction Hydrogen Pd nanotube Catalysis |
| ISSN号 | 2211-2855 |
| 通讯作者 | 毕迎普 |
| 英文摘要 | Herein, we demonstrate that hollow Pd nanotubes could serve as a highly efficient and convenient catalyst for inhibiting Cannizzaro reaction and facilitating hydrogen generation from alkaline formaldehyde solution at room temperature. Moreover, this hollow nanostructure exhibits much higher capability and stability for hydrogen production than conventional Pd nanoparticles. By further optimizing the reaction parameters such as reaction temperature, formaldehyde concentrations, and NaOH concentrations, the hydrogen generation rates could be further increased. Moreover, except for formaldehyde, other aldehydes, including acetaldehyde, propanal, and benaldehyde, could also produce hydrogen with high efficiencies. Owing to its high efficiency at room temperature, this Pd nanotube based hydrogen generation reaction may serve as an alternate hydrogen supply candidate. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the “Hundred Talents Program” of the Chinese Academy of Science;National Natural Science Foundation of China (21273255;21303232) |
| 语种 | 英语 |
| WOS记录号 | WOS:000340981700013 |
| 公开日期 | 2014-12-11 |
| 源URL | [http://210.77.64.217/handle/362003/6915]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 通讯作者 | Bi YP(毕迎普) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Res Unit Environm Remediat Mat, Tsukuba, Ibaraki 3050047, Japan |
| 推荐引用方式 GB/T 7714 | Hu HY,Jiao ZB,Ye JH,et al. Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes[J]. Nano Energy,2014,8:103-109. |
| APA | Hu HY,Jiao ZB,Ye JH,Lu GX,Bi YP,&毕迎普.(2014).Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes.Nano Energy,8,103-109. |
| MLA | Hu HY,et al."Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes".Nano Energy 8(2014):103-109. |
入库方式： OAI收割
来源：兰州化学物理研究所
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