Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions
文献类型：期刊论文
| 作者 | Wang WL(汪文龙)1,2; Zheng AM(郑安民)3; Zhao PQ(赵培庆)1 ; Xia CG(夏春谷)1; Li FW(李福伟)1,4; Li FW(李福伟)
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| 刊名 | ACS Catalysis
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| 出版日期 | 2014 |
| 卷号 | 4期号:1页码:321-327 |
| 关键词 | N-heterocyclic carbene porous organic polymers synthetic control alkyne hydration cross-coupling |
| ISSN号 | 2155-5435 |
| 通讯作者 | 李福伟 |
| 英文摘要 | The synthetic control and functions of porous organic polymers (POPs) with N-heterocyclic carbene gold(I) (Au-NHC@POPs) are described in this article. A series of Au-NHC@POPs with tunable physical properties such as surface area and pore size distribution were first synthesized via Sonogashira chemistry by differing monomer strut lengths and concentration during polymerization; a controllable transition from nonporous to microporous and the coexistence of micro- and mesoporous structures in the framework were realized by varying the monomer concentration. To explain this phenomenon, we put forward a model assumption of a branch-branch cross effect. Additionally, Au-NHC@POPs1 was found to have superior catalytic activity in alkyne hydration reactions, and the catalyst could be used six times with a slight loss of activity. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21002106;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000329472600038 |
| 公开日期 | 2014-12-22 |
| 源URL | [http://210.77.64.217/handle/362003/7023]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 通讯作者 | Li FW(李福伟) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Chinese Acad Sci, Wuhan Ctr Magnet Resonance, Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Suzhou Inst Nanotech & NanoBion, Suzhou 215123, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang WL,Zheng AM,Zhao PQ,et al. Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions[J]. ACS Catalysis,2014,4(1):321-327. |
| APA | Wang WL,Zheng AM,Zhao PQ,Xia CG,Li FW,&李福伟.(2014).Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions.ACS Catalysis,4(1),321-327. |
| MLA | Wang WL,et al."Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions".ACS Catalysis 4.1(2014):321-327. |
入库方式： OAI收割
来源：兰州化学物理研究所
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