NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides
文献类型：期刊论文
| 作者 | Zheng SZ(郑书展); Wang Y(汪妍); Zhang CY(张春艳) ; Liu JH(刘建华); Xia CG(夏春谷); Xia CG(夏春谷); Liu JH(刘建华)
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| 刊名 | Applied Organometallic Chemistry
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| 出版日期 | 2014 |
| 卷号 | 28期号:1页码:48-53 |
| 关键词 | N-heterocyclic carbene palladium complexes double carbonylation aryl iodides α-keto amides |
| ISSN号 | 0268-2605 |
| 通讯作者 | 刘建华 ; 夏春谷 |
| 英文摘要 | A series of palladium–NHC compounds were prepared and their catalytic activity in the double carbonylation of aryl iodides to synthesize α-keto amides were examined. Palladium complexes bearing mixed NHC–phosphine exhibited high efficiency for the double carbonylation reaction. The effects of different solvents, base, temperature, carbon monoxide (CO), pressure, various amine and aryl iodides were investigated. Both electron-rich and electron-deficient aryl iodides afforded the corresponding substituted α-keto amides in moderate to good yields. A possible mechanism was also proposed. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21073209;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000328226600007 |
| 公开日期 | 2014-10-16 |
| 源URL | [http://210.77.64.217/handle/362003/6522]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Xia CG(夏春谷); Liu JH(刘建华) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng SZ,Wang Y,Zhang CY,et al. NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides[J]. Applied Organometallic Chemistry,2014,28(1):48-53. |
| APA | Zheng SZ.,Wang Y.,Zhang CY.,Liu JH.,Xia CG.,...&刘建华.(2014).NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides.Applied Organometallic Chemistry,28(1),48-53. |
| MLA | Zheng SZ,et al."NHC-Pd complex-catalyzed double carbonylation of aryl iodides with secondary amines to α-keto amides".Applied Organometallic Chemistry 28.1(2014):48-53. |
入库方式： OAI收割
来源：兰州化学物理研究所
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