Synthesis and Physicochemical Properties of Two SO3H-Functionalized Ionic Liquids with Hydrogen Sulfate Anion
文献类型：期刊论文
| 作者 | Meng YL(孟雅莉); Liu JM(刘佳梅) ; Li Z(李臻); Wei HM(魏焕梅); Li Z(李臻)
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| 刊名 | Journal of Chemical and Engineering Data
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| 出版日期 | 2014 |
| 卷号 | 59期号:7页码:2186-2195 |
| ISSN号 | 0021-9568 |
| 通讯作者 | 李臻 |
| 英文摘要 | Two SO3H-functionalized ionic liquids (ILs), N-isobutyl-3-sulfopropan-1-aminium hydrogen sulfate [IBAC3S]HSO4 and N-isobutyl-4-sulfobutan-1-aminium hydrogen sulfate [IBAC4S]HSO4, were synthesized and characterized by NMR and HR-MS. The thermal properties and acidities were analyzed. Density, dynamic viscosity, surface tension, conductivity, and refractive index of the IL were studied as a function of temperature. The physicochemical properties, namely molecular volume, isobaric coefficients of thermal expansion, standard entropy, critical temperature, molar free volume, interstice volume, etc. of the IL were estimated according to the reported empirical and thermodynamic equations. On the basis of the Walden rule, the ionicty of the two SO3H-functionalized ionic liquids was assessed by the product of molar conductivity and viscosity. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Key Basic Research Program of China (973 Program, Grant 2011CB201404);the National Natural Science Foundation of China (Grant 21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000338981000008 |
| 公开日期 | 2014-10-23 |
| 源URL | [http://210.77.64.217/handle/362003/6591]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Li Z(李臻) |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng YL,Liu JM,Li Z,et al. Synthesis and Physicochemical Properties of Two SO3H-Functionalized Ionic Liquids with Hydrogen Sulfate Anion[J]. Journal of Chemical and Engineering Data,2014,59(7):2186-2195. |
| APA | Meng YL,Liu JM,Li Z,Wei HM,&李臻.(2014).Synthesis and Physicochemical Properties of Two SO3H-Functionalized Ionic Liquids with Hydrogen Sulfate Anion.Journal of Chemical and Engineering Data,59(7),2186-2195. |
| MLA | Meng YL,et al."Synthesis and Physicochemical Properties of Two SO3H-Functionalized Ionic Liquids with Hydrogen Sulfate Anion".Journal of Chemical and Engineering Data 59.7(2014):2186-2195. |
入库方式： OAI收割
来源：兰州化学物理研究所
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