Significant roles of mesostructure and basic modifier for ordered mesoporous Ni/CaO–Al2O3 catalyst towards CO2 reforming of CH4
文献类型：期刊论文
| 作者 | Xu LL(徐磊磊) ; Miao ZC(苗智超); Song HL(宋焕玲); Chen W(陈伟); Chou LJ(丑凌军); Chou LJ(丑凌军); Xu LL(徐磊磊)
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| 刊名 | Catalysis Science & Technology
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| 出版日期 | 2014 |
| 卷号 | 4期号:6页码:1759-1770 |
| ISSN号 | 2044-4753 |
| 通讯作者 | 徐磊磊 ; 陈伟 ; 丑凌军 |
| 英文摘要 | An ordered mesoporous CaO–Al2O3 composite oxide had been designed and prepared via improved evaporation induced self-assemble strategy (EISA). The resultant material was utilized as the support of Ni based catalyst for CO2 reforming of CH4. In order to study the roles of the ordered mesopore structure and basic modifier in promoting the catalytic properties toward the CO2 reforming of CH4 reaction, non-mesoporous CaO–Al2O3 without ordered mesostructure and ordered mesoporous Al2O3 without basic modifier were also synthesized, respectively. It was found that both the ordered mesostructure and CaO basic modifier showed significant effects in promoting catalytic activity, stability and suppressing the carbon deposition during their 100 h long term stability tests. Compared with traditional supported catalysts, the confinement effect of the mesoporous catalysts could effectively inhibit the thermal sintering of the Ni particles. Furthermore, the sorts of coke species over the spent catalysts and the mechanism of catalyst deactivation were also carefully investigated. Therefore, the present ordered mesoporous CaO–Al2O3 composite oxide will be a potential carrier for Ni-based catalysts for CO2 reforming of CH4 and even other reactions. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Basic Research Program of PR China (no. 2011CB201404);the National Natural Science Foundation of China (no. 21133011;21373244) |
| 语种 | 英语 |
| 公开日期 | 2014-11-20 |
| 源URL | [http://210.77.64.217/handle/362003/6722]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Chou LJ(丑凌军); Xu LL(徐磊磊) |
| 推荐引用方式 GB/T 7714 | Xu LL,Miao ZC,Song HL,et al. Significant roles of mesostructure and basic modifier for ordered mesoporous Ni/CaO–Al2O3 catalyst towards CO2 reforming of CH4[J]. Catalysis Science & Technology,2014,4(6):1759-1770. |
| APA | Xu LL.,Miao ZC.,Song HL.,Chen W.,Chou LJ.,...&徐磊磊.(2014).Significant roles of mesostructure and basic modifier for ordered mesoporous Ni/CaO–Al2O3 catalyst towards CO2 reforming of CH4.Catalysis Science & Technology,4(6),1759-1770. |
| MLA | Xu LL,et al."Significant roles of mesostructure and basic modifier for ordered mesoporous Ni/CaO–Al2O3 catalyst towards CO2 reforming of CH4".Catalysis Science & Technology 4.6(2014):1759-1770. |
入库方式： OAI收割
来源：兰州化学物理研究所
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