The WS₂–Ag composite films were prepared by radio frequency co-sputtering method. The effects of alloying Ag content on composition, microstructure, mechanical properties and friction behaviors have been analyzed by X-ray photoelectron spectroscopy (XPS), grazing incidence X-ray diffraction (GIXRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS) and high resolution transmission electron microscope (HRTEM), scratch tester, nano-indentation tester and ball-on-disk tribo-tester. The Ag addition was in present of nanocrystalline phase in the boundary of the crystalline WS₂ matrix and induced morphology change, but could not completely prevent the columnar platelets. The columnar platelet was composed of a great deal of nanocrystalline and a small amount of amorphous WS₂ phase. There were no substantial variations in the hardness of the composite films when the Ag content was in the range of 0–20.3 at.%. The suitable amount of Ag content was benefited for improving the film adhesive strength and wear resistance both in vacuum and humid air environment. Particularly, the composite film with 9.0 at.% Ag exhibited the longest wear life (about 7.6 × 10⁵ cycles in vacuum, 6.7 × 10⁵ cycles in humid air) under high Hertzian contact pressure (as high as 1.0 GPa). Thewearmechanismwas discussed in terms of the rearrangement ofwear track and formation of transfer film.