Shape controlled synthesis and formation mechanism of Y-2(C2O4)(3) and Eu3+-Y2O3 phases via hydrothermal microemulsion
文献类型:期刊论文
作者 | Chen TD(陈铁旦)1,2,3; Xia YQ(夏延秋)1![]() |
刊名 | Materials Science in Semiconductor Processing
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出版日期 | 2014 |
卷号 | 19页码:1-5 |
关键词 | Yttrium oxalate Hydrothermal microemulsion Calcined products Red luminescence |
ISSN号 | 1369-8001 |
通讯作者 | 夏延秋 |
英文摘要 | The flat or truncated flat cube Y2O3 precursor powders were synthesized in a reverse microemulsion and hydrothermal. Hexadecyl Trimethyl Ammonium Bromide (CTAB) and Organophosphate (OP) were used as the mixed surfactants, n-pentanol was used as assistant, and cyclohexane was used as oil phase. Y(NO3)3 and Na2C2O4 solution were used as the water-phrase and starting materials. The resulting products were characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FESEM), d thermogravimetric – differential scanning calorimetry (TG–DSC), and photoluminescence spectroscopy (PL). The results show that the monoclinic rod-like Y2(C2O4)3 have been obtained via hydrothermal microemulsion and the sizes of the particles were diameters of 100 nm and lengths up to about 1–2 μm. The precursor calcined products were doped with Eu3+, and the prepared phosphors showed well-defined red luminescence due to radiative transitions from 5D0 to 7FJ (J=1, 2) levels of Eu3+ ions. Furthermore, We reported Eu3+–Y2O3 phases represented a new class of optically active materials. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000331676200001 |
公开日期 | 2014-12-05 |
源URL | [http://210.77.64.217/handle/362003/6854] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Huaibei Normal Univ, Sch Chem & Mat Sci, Huaibei 235000, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Chen TD,Xia YQ. Shape controlled synthesis and formation mechanism of Y-2(C2O4)(3) and Eu3+-Y2O3 phases via hydrothermal microemulsion[J]. Materials Science in Semiconductor Processing,2014,19:1-5. |
APA | Chen TD,&Xia YQ.(2014).Shape controlled synthesis and formation mechanism of Y-2(C2O4)(3) and Eu3+-Y2O3 phases via hydrothermal microemulsion.Materials Science in Semiconductor Processing,19,1-5. |
MLA | Chen TD,et al."Shape controlled synthesis and formation mechanism of Y-2(C2O4)(3) and Eu3+-Y2O3 phases via hydrothermal microemulsion".Materials Science in Semiconductor Processing 19(2014):1-5. |
入库方式: OAI收割
来源:兰州化学物理研究所
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