Cross-linked starch-based polymer as an SPE material for the determination of nitrophenols at trace levels in environmental water
文献类型：SCI/SSCI论文
| 作者 | Zhang Q.; Liang T. |
| 发表日期 | 2014 |
| 关键词 | Cross-linked starch Nitrophenols SPE Water solid-phase extraction aqueous-solutions carbon nanotubes graft copolymer adsorption ions microextraction equilibrium performance adsorbent |
| 英文摘要 | SPE using a cross-linked starch-based polymer (CSMDI) as an adsorbent for the determination of four nitrophenols at trace levels from aqueous solution was investigated. The CSMDI was synthesized from native starch using 4,4'-methylenebisphenyldiisocyanate as a cross-linking agent in dry DMF. Parameters affecting the extraction efficiency including the pH of the water sample, type of eluent and its volume, flow rate, sample volume, and methanol content were investigated and optimized. The optimized results exhibited excellent linear relationships (R-2 > 0.995) for all the nitrophenols over the range of 2.0-200 ng/mL, with the RSD values in the range of 2.9-5.7% (n = 5). The LODs ranged from 0.08-0.34 ng/mL (S/N = 3) for the four nitrophenols tested under optimum conditions. The developed method has been successfully applied for the analysis of several real environmental water samples including tap, river, and reservoir water. These results indicated that the CSMDI had a tremendous potential for the enrichment and determination of nitrophenols at trace levels in environmental water samples. |
| 出处 | Journal of Separation Science |
| 卷 | 37 |
| 期 | 3 |
| 页 | 257-264 |
| 收录类别 | SCI |
| 语种 | 英语 |
| ISSN号 | 1615-9306 |
| 源URL | [http://ir.igsnrr.ac.cn/handle/311030/29407]  |
| 专题 | 地理科学与资源研究所_历年回溯文献 |
| 推荐引用方式 GB/T 7714 | Zhang Q.,Liang T.. Cross-linked starch-based polymer as an SPE material for the determination of nitrophenols at trace levels in environmental water. 2014. |
入库方式： OAI收割
来源：地理科学与资源研究所
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